N-aryl-uracils based Herbicides

ABSTRACT

The invention relates to novel herbicidal active compound combinations which comprise, on the one hand, known N-aryl-uracils and, on the other hand, known herbicidally active compounds and/or compounds which improve crop plant compatibility, which combinations can be used with particularly good results for controlling monocotyledonous and dicotyledonous weeds in various crops of useful plants, but also for controlling monocotyledonous and dicotyledonous weeds in the semi- and non-selective area.

[0001] The invention relates to novel herbicidal active compound combinations comprising, on the one hand, known N-aryl-uracils and, on the other hand, known herbicidally active compounds and/or compounds which improve crop plant compatibility, which combinations can be used with particularly good results for controlling monocotyledonous and dicotyledonous weeds in various crops of useful plants, but also for controlling monocotyledonous and dicotyledonous weeds in the semi- and non-selective field.

[0002] N-aryl-uracils are, as herbicidally active compounds, subject of a number of patent applications (cf. EP-A-408382, EP-A-473551, EP-A-563384, EP-A-648749, U.S. Pat. No. 4,943,309, U.S. Pat. No. 5,084,084, U.S. Pat. No. 5,127,935, U.S. Pat. No. 5,759,957, WO-A-91/00278, WO-A-95/29168, WO-A-95/30661, WO-A-96/35679, WO-A-97/01541, WO-A-98/25909). However, the known N-aryl-uracils have a number of gaps in their activity.

[0003] A number of herbicidally active compound combinations based on N-aryl-uracils have also been disclosed (cf. DE-A-4437197, DE-A-19915013, DE-A-19919951, EP-A-714602, WO-A-96/07323, WO-A-96/08151, JP-A-11189506). However, likewise, the properties of these active compound combinations are not entirely satisfactory.

[0004] Surprisingly, it has now been found that a number of known active compounds from the group of the N-aryl-uracils, when used together with known herbicidally active compounds, show synergistic effects with respect to the activity against weeds and can be used particularly advantageously as broadly active combination preparations for the selective control of monocotyledonous and dicotyledonous weeds in crops of useful plants, such as, for example, cotton, cereals, grass/pasture land, maize, lawn (“turf”), rice, soyabeans, sunflowers and sugar cane, but also for controlling monocotyledonous and dicotyledonous weeds in the semi- and non-selective field.

[0005] The present invention provides herbicidal compositions, characterized in that they comprise an effective amount of an active compound combination comprising

[0006] (a) at least one N-aryl-uracil of the formula (I)

[0007] in which

[0008] R¹ represents hydrogen, amino or optionally cyano-, halogen- or C₁-C₄-alkoxy-substituted alkyl having 1 to 5 carbon atoms,

[0009] R² represents optionally halogen-substituted alkyl having 1 to 5 carbon atoms,

[0010] R³ represents hydrogen, halogen or optionally halogen-substituted alkyl having 1 to 5 carbon atoms,

[0011] R⁴ represents hydrogen, cyano or halogen,

[0012] R⁵ represents cyano, thiocarbamoyl or halogen, and

[0013] R⁶ represents nitro, cyano, carboxyl, carbamoyl, thiocarbamoyl, hydroxyl, mercapto, amino, hydroxyamino, aminosulphonyl, halogen, represents in each case optionally cyano-, hydroxyl-, C₁-C₄-alkoxy-, C₁-C₄-alkyl-carbonyl-, C₁-C₄-alkoxy-carbonyl-, C₂-C₄-alkenyloxy-carbonyl-, C₂-C₄-alkinyloxy-carbonyl-, C₁-C₄-alkylamino-carbonyl-, di-(C₁-C₄-alkyl)-amino-carbonyl-, phenoxycarbonyl- and/or phenylaminocarbonyl-substituted alkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl, alkylcarbonyl, alkoxycarbonyl or alkylamino having in each case up to 6 carbon atoms, represents in each case optionally cyano-, carboxyl-, halogen- and/or C₁-C₄-alkoxy-carbonyl-substituted alkenyl, alkinyl, alkenyloxy or alkinyloxy having in each case up to 6 carbon atoms, represents in each case optionally halogen- or C₁-C₄-alkoxy-substituted alkylcarbonylamino, alkoxycarbonylamino, alkylsulphonylamino, N,N-bis-alkylsulphonyl-amino or N-alkylcarbonyl-N-alkylsulphonyl-amino having in each case up to 6 carbon atoms in the alkyl groups, or represents phenyloxy, naphthyloxy, N-phenylcarbonyl-N-alkylsulphonyl-amino, N-pyridylcarbonyl-N-alkylsulphonyl-amino, N-furylcarbonyl-N-alkylsulphonyl-amino or N-thienylcarbonyl-N-alkylsulphonyl-amino having in each case up to 6 carbon atoms in the alkyl groups and being in each case optionally substituted by cyano or halogen, or by C₁-C₄-alkyl, C₁-C₄-alkoxy or C₁-C₄-alkoxy-carbonyl (which are in each case optionally substituted by C₁-C₄-alkoxy-carbonyl, C₃-C₄-alkenyloxy-carbonyl or C₃-C₄-alkinyloxy-carbonyl),

[0014] (“active compounds of Group 1”)

[0015] and

[0016] (b) at least one compound from a second group of herbicides comprising the active compounds listed below:

[0017] 2-chloro-N-(ethoxymethyl)-N-(2-ethyl-6-methyl-phenyl)-acetamide (acetochlor), 5-(2-chloro-4-trifluoromethyl-phenoxy)-2-nitro-benzoic acid sodium salt (acifluorfen-sodium), 2-chloro-6-nitro-3-phenoxy-benzenamine (aclonifen), 2-chloro-N-(methoxymethyl)-N-(2,6-diethyl-phenyl)-acetamide (alachlor), N-ethyl-N′-i-propyl-6-methylthio-1,3,5-triazine-2,4-diamine (ametryn), 4-amino-N-(1,1-dimethyl-ethyl)-4,5-dihydro-3-(1-methyl-ethyl)-5-oxo-1H-1,2,4-triazole-1-carboxamide (amicarbazone), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(N-methyl-N-methylsulphonyl-sulphamoyl)-urea (amidosulfuron), 1H-1,2,4-triazol-3-amine (amitrole), 6-chloro-4-ethyl-amino-2-isopropylamino-1,3,5-triazine (atrazine), 2-[2,4-dichloro-5-(2-propinyloxy)-phenyl]-5,6,7,8-tetrahydro-1,2,4-triazolo-[4,3-a]-pyridin-3(2H)-one (azafenidin), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-[1-methyl-4-(2-methyl-2H-tetrazol-5-yl)-1H-pyrazol-5-ylsulphonyl]-urea (azimsulfuron), N-benzyl-2-(4-fluoro-3-trifluoromethyl-phenoxy)-butanamide (beflubutamid), 4-chloro-2-oxo-3(2H)-benzothiazoleacetic acid (benazolin), N-butyl-N-ethyl-2,6-dinitro-4-trifluoromethyl-benzenamine (benfluralin), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(2-methoxycarbonyl-phenylmethyl-sulphonyl)-urea (bensulfuron), methyl 2-[2-[4-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1(2H)-pyrimidinyl)phenoxy]methyl]-5-ethyl-phenoxy-propanoate (benzfendizone), 3-(2-chloro-4-methylsulphonyl-benzoyl)-4-phenylthio-bicyclo-[3.2.1]-oct-3-en-2-one (benzobicyclon), ethyl N-benzoyl-N-(3,4-dichloro-phenyl)-DL-alaninate (benzoylprop-ethyl), 3-i-propyl-1H-2,1,3-benzothiadiazin-4(3H)-one (bentazone), methyl 5-(2,4-dichloro-phenoxy)-2-nitro-benzoate (bifenox), 2,6-bis-(4,6-dimethoxy-pyrimidin-2-yl-oxy)-benzoic acid sodium salt (bispyribac-sodium), 5-bromo-6-methyl-3-(1-methyl-propyl)-2,4(1H,3H)pyrimidinedione (bromacil), 2-bromo-3,3-dimethyl-N-(1-methyl-1-phenyl-ethyl)-butanamide (bromobutide), O-(2,4-dinitro-phenyl) 3,5-dibromo-4-hydroxy-benzaldehyde-oxime (bromofenoxim), 3,5-dibromo-4-hydroxy-benzonitrile (bromoxynil), N-butoxymethyl-2-chloro-N-(2,6-diethyl-phenyl)-acetamide (butachlor), [1,1-dimethyl-2-oxo-2-(2-propenyloxy)]-ethyl 2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H)-pyrimidinyl)-benzoate (butafenacil-allyl), 2-(1-ethoximino-propyl)-3-hydroxy-5-[2,4,6-trimethyl-3-(1-oxo-butyl)-phenyl]-2-cyclohexen-1-one (butroxydim), S-ethyl bis-(2-methyl-propyl)-thiocarbamate (butylate), N,N-diethyl-3-(2,4,6-trimethyl-phenylsulphonyl)-1H-1,2,4-triazole-1-carboxamide (cafenstrole), 2-[1-[(3-chloro-2-propenyl)-oxy-imino]-propyl]-3-hydroxy-5-(tetrahydro-2H-pyran-4-yl)-2-cyclohexen-1-one (caloxydim, tepraloxydim), 2-(4-chloro-2-fluoro-5-(2-chloro-2-ethoxycarbonyl-ethyl)-phenyl)-4-difluoromethyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one (carfentrazone-ethyl), 2,4-dichloro-1-(3-methoxy-4-nitro-phenoxy)-benzene (chlomethoxyfen), 3-amino-2,5-dichloro-benzoic acid (chloramben), N-(4-chloro-6-methoxy-pyrimidin-2-yl)-N′-(2-ethoxycarbonyl-phenylsulphonyl)-urea (chlorimuron-ethyl), 1,3,5-trichloro-2-(4-nitro-phenoxy)-benzene (chlornitrofen), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N′-(2-chloro-phenylsulphonyl)-urea (chlorsulfuron), N′-(3-chloro-4-methyl-phenyl)-N,N-dimethyl-urea (chlortoluron), ethyl 2-chloro-3-[2-chloro-5-(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)-phenyl]-2-propanoate (cinidon-ethyl), N-(4,6-dimethoxy-1,3,5-triazin-2-yl)-N′-(2-(2-methoxy-ethoxy)-phenylsulphonyl)-urea (cinosulfuron), 2-[1-[2-(4-chloro-phenoxy)-propoxyamino]butyl]-5-(tetrahydro-2H-thiopyran-3-yl)-1,3-cyclohexanedione (clefoxydim), (E,E)-(+)-2-[1-[[(3-chloro-2-propenyl)-oxy]-imino]-propyl]-3-hydroxy-2-cyclohexen-1-one (clethodim), prop-2-inyl (R)-2-[4-(5-chloro-3-fluoro-pyridin-2-yl-oxy)-phenoxy]-propanoate (clodinafop-propargyl), 3,6-dichloro-pyridine-2-carboxylic acid (clopyralid), methyl 3-chloro-2-[(5-ethoxy-7-fluoro-[1,2,4]triazolo-[1,5-c]pyrimidin-2-yl-sulphonyl)-amino]-benzoate (cloransulam-methyl), 2-chloro-4-ethylamino-6-(1-cyano-1-methyl-ethylamino)-1,3,5-triazine (cyanazine), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(2-cyclopropylcarbonyl-phenylsulphonyl)-urea (cyclosulfamuron), 2-(1-ethoximinobutyl)-3-hydroxy-5-(tetrahydro-2H-thiopyran-3-yl)-2-cyclohexen-1-one (cycloxydim), butyl (R)-2-[4-(4-cyano-2-fluoro-phenoxy)-phenoxy]-propanoate (cyhalofop-butyl), 2,4-dichloro-phenoxyacetic acid (2,4-D), 3,6-dichloro-2-methoxy-benzoic acid (dicamba), (R)-2-(2,4-dichloro-phenoxy)-propanoic acid (dichlorprop-P), methyl-2-[4-(2,4-dichloro-phenoxy)-phenoxy]-propanoate (diclofop-methyl), N-(2,6-dichloro-phenyl)-5-ethoxy-7-fluoro-[1,2,4]-triazolo-[1,5-c]-pyrimidine-2-sulphonamide (diclosulam), 1,2-dimethyl-3,5-diphenyl-1H-pyrazolium methylsulphate (difenzoquat), N-(2,4-difluoro-phenyl)-2-(3-trifluoromethyl-phenoxy)-pyridine-3-carboxamide (diflufenican), 2-[1-[(3,5-difluoro-phenyl)-amino-carbonyl-hydrazono]-ethyl]-pyridine-3-carboxylic acid (diflufenzopyr), S-(1-methyl-1-phenyl-ethyl) 1-piperidine-carbothioate (dimepiperate), 2-chloro-N-(2,6-dimethyl-phenyl)-N-(2-methoxy-ethyl)-acetamide (dimethachlor), (S—) 2-chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methyl-ethyl)-acetamide (S—) (dimethenamid), 2-amino-4-(1-fluoro-1-methyl-ethyl)-6-(1-methyl-2-(3,5-dimethyl-phenoxy)-ethylamino)-1,3,5-triazine (dimexyflam), N3,N3-diethyl-2,4-dinitro-6-trifluoromethyl-1,3-diamino-benzene (dinitramine), 6,7-dihydro-dipyrido[1,2-a:2′,1′-c]pyrazinediium (diquat), S,S-dimethyl 2-difluoromethyl-4-i-butyl-6-trifluoromethyl-pyridine-3,5-dicarbothioate (dithiopyr), N′-(3,4-dichloro-phenyl)-N,N-dimethyl-urea (diuron), 2-[2-(3-chlorophenyl)-oxiranylmethyl]-2-ethyl-1H-indene-1,3(2H)-dione (epropodan), S-ethyl di-propylthiocarbamate (EPTC), S-(phenylmethyl) N-ethyl-N-(1,2-dimethyl-propyl)-thiocarbamate (esprocarb), N-ethyl-N-(2-methyl-2-propenyl)-2,6-dinitro-4-trifluoromethyl-benzenamine (ethalfluralin), 2-ethoxy-1-methyl-2-oxoethyl (S)-2-chloro-5-(2-chloro-4-trifluoromethyl-phenoxy)-benzoate (ethoxyfen), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(2-ethoxy-phenoxysulphonyl)-urea (ethoxysulfuron), ethyl (R)-2-[4-(6-chloro-benzoxazol-2-yl-oxy)-phenoxy]-propanoate (fenoxaprop-(P)-ethyl), 4-(2-chloro-phenyl)-N-cyclohexyl-N-ethyl-4,5-dihydro-5-oxo-1H-tetrazole-1-carboxamide (fentrazamid), isopropyl N-benzoyl-N-(3-chloro-4-fluoro-phenyl)-DL-alaninate (flamprop-isopropyl), isopropyl N-benzoyl-N-(3-chloro-4-fluoro-phenyl)-L-alaninate (flamprop-isopropyl-L), methyl N-benzoyl-N-(3-chloro-4-fluoro-phenoxy)-DL-alaninate (flamprop-methyl), N-(2,6-difluoro-phenyl)-8-fluoro-5-methoxy-[1,2,4]-triazolo-[1,5-c]-pyrimidine-2-sulphonamide (florasulam), butyl (R)-2-[4-(5-trifluoromethyl-pyridin-2-yl-oxy)-phenoxy]-propanoate (fluazifop, -butyl, —P-butyl), i-propyl 5-(4-bromo-1-methyl-5-trifluoromethyl-1H-pyrazol-3-yl)-2-chloro-4-fluoro-benzoate (fluazolate), 4,5-dihydro-3-methoxy-4-methyl-5-oxo-N-[(2-trifluoromethoxy-phenyl)-sulphonyl]-1H-1,2,4-triazole-1-carboxamide sodium salt (flucarbazone-sodium), N-(4-fluoro-phenyl)-N-i-propyl-2-(5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy)-acetamide (flufenacet), N-(2,6-difluoro-phenyl)-5-methyl-1,2,4-triazolo[1,5-a]-pyrimidine-2-sulphonamide (flumetsulam), pentyl [2-chloro-4-fluoro-5-(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)-phenoxy]-acetate (flumiclorac-pentyl), 2-[7-fluoro-3,4-dihydro-3-oxo-4-(2-propinyl)-2H-1,4-benzoxazin-6-yl]-4,5,6,7-tetrahydro-1H-isoindole-1,3-dione (flumioxazin), 2-[4-chloro-2-fluoro-5-[(1-methyl-2-propinyl)-oxy]-phenyl]-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)-dione (flumipropyn), 3-chloro-4-chloromethyl-1-(3-trifluoromethyl-phenyl)-2-pyrrolidinone (fluorochloridone), ethoxycarbonylmethyl 5-(2-chloro-4-trifluoromethyl-phenoxy)-2-nitro-benzoate (fluoroglycofen-ethyl), 1-(4-chloro-3-(2,2,3,3,3-pentafluoro-propoxymethyl)-phenyl)-5-phenyl-1H-1,2,4-triazole-3-carboxamide (flupoxam), 1-isopropyl-2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1(2H)-pyrimidyl)-benzoate (flupropacil), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(3-methoxycarbonyl-6-trifluoromethyl-pyridin-2-yl-sulphonyl)-urea sodium salt (flupyrsulfuron-methyl-sodium), 9-hydroxy-9H-fluorene-9-carboxylic acid (flurenol), (4-amino-3,5-dichloro-6-fluoro-pyridin-2-yl-oxy)-acetic acid (2-butoxy-1-methyl-ethyl ester, 1-methyl-heptyl ester) (fluroxypyr, -butoxypropyl, -meptyl), 5-methylamino-2-phenyl-4-(3-trifluoromethyl-phenyl)-3(2H)-furanone (flurtamone), methyl [(2-chloro-4-fluoro-5-(tetrahydro-3-oxo-1H,3H-[1,3,4]-thiadiazolo-[3,4-a]-pyridazin-1-yliden)-amino)-phenyl]-thio-acetate (fluthiacet-methyl), 5-(2-chloro-4-trifluoromethyl-phenoxy)-N-methylsulphonyl-2-nitro-benzamide (fomesafen), 2-[[[[(4,6-dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-amino]-sulphonyl]-4-formylamino-N,N-dimethyl-benzamide (foramsulfuron), 2-amino-4-(hydroxymethylphosphinyl)-butanoic acid (ammonium salt) (glufosinate-(ammonium)), N-phosphonomethyl-glycine (isopropylammonium salt) (glyphosate, isopropylammonium), (R)-2-[4-(3-chloro-5-trifluoromethyl-pyridin-2-yl-oxy)-phenoxy]-propanoic acid (methyl ester, 2-ethoxyethyl ester, butyl ester) (haloxyfop, -methyl, —P-methyl, -ethoxyethyl, -butyl), 3-cyclohexyl-6-dimethylamino-1-methyl-1,3,5-triazine-2,4(1H,3H)-dione (hexazinone), methyl 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-4-methyl-benzoate (imazamethabenz-methyl), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5-methyl-pyridine-3-carboxylic acid (imazamethapyr), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5-methoxymethyl-pyridine-3-carboxylic acid (imazamox), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-quinoline-3-carboxylic acid (imazaquin), 2-(4,5-dihydro-4-methyl-4-i-propyl-5-oxo-1H-imidazol-2-yl)-5-ethyl-pyridine-3-carboxylic acid (imazethapyr), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(2-chloro-imidazo[1,2-a]-pyridin-3-yl-sulphonyl)-urea (imazosulfuron), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N′-(5-iodo-2-methoxycarbonyl-phenylsulphonyl)-urea sodium salt (iodosulfuron-methyl-sodium), 4-hydroxy-3,5-diiodo-benzonitrile (ioxynil), N,N-dimethyl-N′-(4-isopropyl-phenyl)-urea (isoproturon), N-(3-(1-ethyl-1-methyl-propyl)-isoxazol-5-yl)-2,6-dimethoxy-benzamide (isoxaben), (4-chloro-2-methylsulphonyl-phenyl)-(5-cyclopropyl-isoxazol-4-yl)-methanone (isoxachlortole), (5-cyclopropyl-isoxazol-4-yl)-(2-methylsulphonyl-4-trifluoromethyl-phenyl)-methanone (isoxaflutole), 2-[2-[4-[(3,5-dichloro-2-pyridinyl)-oxy]-phenoxy]-1-oxo-propyl]-isoxazolidine (isoxapyri-fop), (2-ethoxy-1-methyl-2-oxo-ethyl)-5-(2-chloro-4-trifluoromethyl-phenoxy)-2-nitro-benzoate (lactofen), N′-(3,4-dichloro-phenyl)-N-methoxy-N-methyl-urea (linuron), (4-chloro-2-methyl-phenoxy)-acetic acid (MCPA), 2-(4-chloro-2-methyl-phenoxy)-propionic acid (mecoprop), 2-(2-benzothiazolyloxy)-N-methyl-N-phenyl-acetamide (mefenacet), methyl 2-[[[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]amino]sulphonyl]-4-[[(methylsulphonyl)amino]methyl]-benzoate (mesosulfuron), 2-(4-methylsulphonyl-2-nitro-benzoyl)-1,3-cyclohexanedione (mesotrione), 4-amino-3-methyl-6-phenyl-1,2,4-triazin-5(4H)-one (metamitron), 2-chloro-N-(2,6-dimethyl-phenyl)-N-(1H-pyrazol-1-yl-methyl)-acetamide (metazachlor), N′-(4-(3,4-dihydro-2-methoxy-2,4,4-trimethyl-2H-1-benzopyran-7-yl-oxy)-phenyl)-N-methoxy-N-methyl-urea (metobenzuron), N′-(4-bromophenyl)-N-methoxy-N-methyl urea (metobromuron), (S)-2-chloro-N-(2-ethyl-6-methyl-phenyl)-N-(2-methoxy-1-methylethyl)-acetamide (metolachlor, S-metolachlor), N-(2,6-dichloro-3-methyl-phenyl)-5,7-dimethoxy-1,2,4-triazolo[1,5-a]-pyrimidine-2-sulphonamide (metosulam), N′-(3-chloro-4-methoxy-phenyl)-N,N-dimethyl-urea (metoxuron), 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one (metribuzin), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N′-(2-methoxycarbonyl-phenylsulphonyl)-urea (metsulfuron-methyl), S-ethyl-hexahydro-1H-azepine-1-carbothioate (molinate), 2-(2-naphthyloxy)-N-phenyl-propanamide (naproanilide), N-butyl-N′-(3,4-dichloro-phenyl)-N-methyl-urea (neburon), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(3-dimethylcarbamoyl-pyridin-2-yl-sulphonyl)-urea (nicosulfuron), 4-chloro-5-methylamino-2-(3-trifluoromethylphenyl)-3(2H)-pyridazinone (norflurazon), S-(2-chloro-benzyl)-N,N-diethyl-thiocarbamate (orbencarb), 4-dipropylamino-3,5-dinitro-benzenesulphonamide (oryzalin), 3-[2,4-dichloro-5-(2-propinyloxy)-phenyl]-5-(t-butyl)-1,3,4-oxadiazol-2(3H)-one (oxadiargyl), 3-[2,4-dichloro-5-(1-methyl-ethoxy)-phenyl]-5-(t-butyl)-1,3,4-oxadiazol-2(3H)-one (oxadiazon), N-(4,6-dimethyl-pyrimidin-2-yl)-N′-(2-oxetan-3-yl-oxycarbonyl-phenylsulphonyl)-urea (oxasulfuron), 3-[1-(3,5-dichloro-phenyl)-1-i-propyl]-2,3-dihydro-6-methyl-5-phenyl-4H-1,3-oxazin-4-one (oxaziclomefone), 2-chloro-1-(3-ethoxy-4-nitro-phenoxy)-4-trifluoromethylbenzene (oxyfluorfen), 1,1′-dimethyl-4,4′-bipyridinium (paraquat), 1-amino-N-(1-ethyl-propyl)-3,4-dimethyl-2,6-dinitro-benzene (pendimethalin), 4-(t-butyl)-N-(1-ethyl-propyl)-2,6-dinitro-benzenamine (pendralin), 4-amino-3,5,6-trichloro-pyridine-2-carboxylic acid (picloram), N-(4-fluoro-phenyl)-6-(3-trifluoromethyl-phenoxy)-pyridine-2-carboxamide (picolinafen), 2-chloro-N-(2,6-diethyl-phenyl)-N-(2-propoxy-ethyl)-acetamide (pretilachlor), N-(4,6-bis-difluoromethoxy-pyrimidin-2-yl)-N′-(2-methoxycarbonyl-phenylsulphonyl)-urea (primisulfuron-methyl), 1-chloro-N-[2-chloro-4-fluoro-5-[(6S,7aR)-6-fluorotetrahydro-1,3-dioxo-1H-pyrrolo[1,2-c]imidazol-2(3H)-yl]-phenyl]-methanesulphonamide (profluazol), 2-chloro-N-isopropyl-N-phenyl-acetamide (propachlor), N-(3,4-dichloro-phenyl)-propanamide (propanil), (R)-[2-[[(1-methylethylidene)-amino]-oxy]-ethyl]-2-[4-(6-chloro-2-quinoxalinyloxy)-phenoxy]-propanoate (propaquizafop), 2-chloro-N-(2-ethyl-6-methyl-phenyl)-N-[(1-methyl-ethoxy)-methyl]-acetamide (propisochlor), methyl 2-[[[(4,5-dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl]-carbonyl]-amino]-sulphonyl]-benzoate sodium salt (propoxycarbazone-sodium), S-phenylmethyl N,N-dipropyl-thiocarbamate (prosulfocarb), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N′-(2-(3,3,3-trifluoro-propyl)-phenylsulphonyl)-urea (prosulfuron), ethyl [2-chloro-5-(4-chloro-5-difluoromethoxy-1-methyl-1H-pyrazol-3-yl)-4-fluoro-phenoxy]-acetate (pyraflufen-ethyl), 1-(3-chloro-4,5,6,7-tetrahydro-pyrazolo[1,5-a]pyridin-2-yl)-5-(methyl-2-propinylamino)-1H-pyrazole-4-carbonitrile (pyrazogyl), 4-(2,4-dichloro-benzoyl)-1,3-dimethyl-5-(4-methyl-phenylsulphonyloxy)-pyrazole (pyrazolate), 4-(2,4-dichloro-benzoyl)-1,3-dimethyl-5-(phenylcarbonylmethoxy)-pyrazole (pyrazoxyfen), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(4-ethoxycarbonyl-1-methyl-pyrazol-5-yl-sulphonyl)-urea (pyrazosulfuron-ethyl), O-[2,6-bis-(4,6-dimethoxy-pyrimidin-2-yl-oxy)-benzoyl] diphenylmethanone-oxime (pyribenzoxim), 6-chloro-3-phenyl-4-pyridazinol (pyridafol), O-(6-chloro-3-phenyl-pyridazin-4-yl)-S-octyl thiocarbonate (pyridate), 6-chloro-3-phenyl-pyridazin-4-ol (pyridatol), 7-[(4,6-dimethoxy-2-pyrimidinyl)-thio]-3-methyl-1(3H)-iso-benzofuranone (Pyriftalid), methyl 2-(4,6-dimethoxy-pyrimidin-2-yl-oxy)-benzoate (pyriminobac-methyl), 2-chloro-6-(4,6-dimethoxy-pyrimidin-2-ylthio)-benzoic acid sodium salt (pyrithiobac-sodium), 3,7-dichloro-quinoline-8-carboxylic acid (quinchlorac), 7-chloro-3-methyl-quinoline-8-carboxylic acid (quinmerac), 2-[4-(6-chloro-2-quinoxalinyloxy)-phenoxy]-propanoic acid (ethyl ester, tetrahydro-2-furanyl-methyl ester) (quizalofop, -ethyl, —P-ethyl, —P-tefuryl), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(3-ethylsulphonyl-pyridin-2-yl-sulphonyl)-urea (rimsulfuron), 2-(1-ethoximinobutyl)-5-(2-ethylthiopropyl)-3-hydroxy-2-cyclohexen-1-one (sethoxydim), 6-chloro-2,4-bis-ethylamino-1,3,5-triazine (simazin), 2-(2-chloro-4-methylsulphonyl-benzoyl)-cyclohexane-1,3-dione (sulcotrione), 2-(2,4-dichloro-5-methylsulphonylamino-phenyl)-4-difluoromethyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one (sulfentrazone), methyl 2-[[[[(4,6-dimethyl-2-pyrimidinyl)amino]carbonyl]amino]sulphonyl]-benzoate (sulfometuron-methyl), N-phosphonomethyl-glycine-trimethylsulphonium (sulfosate), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(2-ethylsulphonyl)-imidazo[1,2-a]pyridine-3-sulphonamide (sulfosulfuron), 6-chloro-4-ethylamino-2-tert-butylamino-1,3,5-triazine (terbuthylazine), 2-tert-butylamino-4-ethylamino-6-methylthio-1,3,5-triazine (terbutryn), 2-chloro-N-(2,6-dimethyl-phenyl)-N-(3-methoxy-2-thienyl-methyl)-acetamide (thenylchlor), methyl 2-difluoromethyl-5-(4,5-dihydro-thiazol-2-yl)-4-(2-methyl-propyl)-6-trifluoromethyl-pyridine-3-carboxylate (thiazopyr), 6-(6,7-dihydro-6,6-dimethyl-3H,5H-pyrrolo[2,1-c]-1,2,4-thiadiazol-3-ylideneamino)-7-fluoro-4-(2-propinyl)-2H-1,4-benzoxazin-3(4H)-one (thidiazimin), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N′-(2-methoxy-carbonyl-thien-3-yl-sulphonyl)-urea (thifensulfuron-methyl), 2-(ethoximino-propyl)-3-hydroxy-5-(2,4,6-trimethyl-phenyl)-2-cyclohexen-1-one (tralkoxydim), S-(2,3,3-trichloro-2-propenyl) diisopropylcarbamothioate (triallate), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N′-[2-(2-chloro-ethoxy)-phenylsulphonyl]-urea (triasulfuron), N-methyl-N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N′-(2-methoxycarbonyl-phenylsulphonyl)-urea (tribenuron-methyl), (3,5,6-trichloro)-pyridin-2-yl-oxy-acetic acid (triclopyr), 2-(3,5-dichloro-phenyl)-2-(2,2,2-trichloro-ethyl)-oxirane (tridiphane), N-[[(4,6-dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-3-(2,2,2-trifluoro-ethoxy)-2-pyridinesulphonamide sodium salt (trifloxysulfuron), 1-amino-2,6-dinitro-N,N-dipropyl-4-trifluoromethyl-benzene (trifluralin), N-[4-dimethylamino-6-(2,2,2-trifluoro-ethoxy)-1,3,5-triazin-2-yl]-N′-(2-methoxycarbonyl-phenylsulphonyl)-urea (triflusulfuron-methyl), N-(4-methoxy-6-trifluoromethoxy-1,3,5-triazin-2-yl)-N′-(2-trifluoromethyl-phenylsulphonyl)-urea (tritosulfuron), N-[[(4,6-dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-3-(N-methyl-N-methylsulphonyl-amino)-2-pyridinesulphonamide, (cf. WO-A-92/10660), 4-[4,5-dihydro-4-methyl-5-oxo-(3-trifluoromethyl)-1H-1,2,4-triazol-1-yl]-2-[(ethylsulphonyl)amino]-5-fluoro-benzencarbothioamide (cf. WO-A-95/30661)

[0018] (“active compounds of Group 2”),

[0019] and/or

[0020] (c) a compound which improves crop plant compatibility, from the group of compounds below:

[0021] 4-dichloroacetyl-1-oxa-4-aza-spiro[4.5]-decane (AD-67), 1-dichloroacetyl-hexahydro-3,3,8a-trimethylpyrrolo[1,2-a]-pyrimidin-6(2H)-one (BAS-145138), 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine (benoxacor), 1-methyl-hexyl 5-chloro-quinoxalin-8-oxy-acetate (cloquintocet-mexyl), α-(cyanomethoximino)-phenylacetonitrile (cyometrinil), 2,4-dichlorophenoxy-acetic acid (2,4-D), 2,2-dichloro-N-(2-oxo-2-(2-propenylamino)-ethyl)-N-(2-propenyl)-acetamide (DKA-24), 2,2-dichloro-N,N-di-2-propenyl-acetamide (dichlormid), N-(4-methyl-phenyl)-N′-(1-methyl-1-phenyl-ethyl)-urea (dymron), 4,6-dichloro-2-phenyl-pyrimidine (fenclorim), ethyl 1-(2,4-dichloro-phenyl)-5-trichloromethyl-1H-1,2,4-triazole-3-carboxylate (fenchlorazol-ethyl), phenylmethyl 2-chloro-4-trifluoromethyl-thiazole-5-carboxylate (flurazole), 4-chloro-N-(1,3-dioxolan-2-yl-methoxy)-α-trifluoro-acetophenone oxime (fluxofenim), 3-dichloroacetyl-5-(2-furanyl)-2,2-dimethyl-oxazolidine (furilazole, MON-13900), ethyl 4,5-dihydro-5,5-diphenyl-3-isoxazolecarboxylate (isoxadifen-ethyl), (4-chloro-2-methyl-phenoxy)-acetic acid (MCPA), (+−)-2-(4-chloro-2-methylphenoxy)propanoic acid (mecoprop), diethyl 1-(2,4-dichlorophenyl)-4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylate (mefenpyr-diethyl), 2-dichloromethyl-2-methyl-1,3-dioxolane (MG-191), 1,8-naphthalic anhydride, α-(1,3-dioxolan-2-yl-methoximino)-phenylacetonitrile (oxabetrinil), 2,2-dichloro-N-(1,3-dioxolan-2-yl-methyl)-N-(2-propenyl)-acetamide (PPG-1292), 3-dichloroacetyl-2,2,5-trimethyl-oxazolidine (R-29148), N-cyclopropyl-4-[[(2-methoxy-5-methylbenzoyl)-amino]-sulphonyl]-benzamide, (WO-A-99/66795), N-[(4-methoxyacetylamino)-phenyl]-sulphonyl-2-methoxy-benzamide (WO-A-99/66795) and N-[(4-methylaminocarbonylamino)-phenyl]-sulphonyl-2-methoxy-benzamide (WO-A-99/66795)

[0022] (“active compounds of Group 3”).

[0023] Preferred meanings of the radicals listed in the formula (I) shown above are illustrated below.

[0024] R¹ preferably represents hydrogen, amino or in each case optionally cyano-, fluorine-, chlorine- methoxy- or ethoxy-substituted methyl, ethyl, n- or i-propyl.

[0025] R² preferably represents in each case optionally fluorine- and/or chlorine-substituted methyl, ethyl, n- or i-propyl.

[0026] R³ preferably represents hydrogen, fluorine, chlorine, bromine or in each case optionally fluorine- and/or chlorine-substituted methyl, ethyl, n- or i-propyl.

[0027] R⁴ preferably represents hydrogen, cyano, fluorine, chlorine or bromine.

[0028] R⁵ preferably represents cyano, thiocarbamoyl, fluorine, chlorine or bromine.

[0029] R⁶ preferably represents nitro, cyano, carboxyl, carbamoyl, thiocarbamoyl, hydroxyl, mercapto, amino, hydroxyamino, aminosulphonyl, fluorine, chlorine, bromine, represents in each case optionally cyano-, carboxyl-, hydroxyl-, methoxy-, ethoxy-, n- or i-propoxy-, acetyl-, propionyl-, n- or i-butyroyl-, methoxycarbonyl-, ethoxycarbonyl-, n- or i-propoxycarbonyl-, allyloxycarbonyl- or propargyloxycarbonyl-substituted methyl, ethyl, n- or i-propyl, n-, i- or s-butyl, methoxy, ethoxy, n- or i-propoxy, n-, i- or s-butoxy, methylthio, ethylthio, n- or i-propylthio, n-, i- or s-butylthio, methylsulphinyl, ethylsulphinyl, methylsulphonyl, ethylsulphonyl, acetyl, propionyl, n- or i-butyroyl, methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl, methylamino, ethylamino, n- or i-propylamino, n-, i- or s-butylamino, represents in each case optionally cyano-, carboxyl-, fluorine-, chlorine-, bromine-, methoxycarbonyl- and/or ethoxycarbonyl-substituted ethenyl, propenyl, butenyl, ethinyl, propinyl, butinyl, propenyloxy, butenyloxy, propinyloxy or butinyloxy, represents in each case optionally fluorine- and/or chlorine-, methoxy-, ethoxy-, n- or i-propoxy-substituted acetylamino, propionylamino, n- or i-butyroylamino, methoxycarbonylamino, ethoxycarbonylamino, n- or i-propoxycarbonylamino, methylsulphonylamino, ethylsulphonylamino, n- or i-propylsulphonylamino, n-, i-, s- or t-butylsulphonylamino, N,N-bis-methylsulphonyl-amino, N,N-bis-ethylsulphonyl-amino, N-ethylsulphonyl-N-methylsulphonyl-amino, N-methylsulphonyl-N-n-propylsulphonyl-amino, N-methylsulphonyl-N-i-propylsulphonyl-amino, N-acetyl-N-methylsulphonyl-amino, N-propionyl-N-methylsulphonyl-amino, N-n-butyroyl-N-methylsulphonyl-amino, N-i-butyroyl-N-methylsulphonyl-amino, N-s-butyroyl-N-methylsulphonyl-amino, N-t-butyroyl-N-methylsulphonyl-amino, N-(2,2-dimethyl-propanoyl)-N-ethylsulphonyl-amino, N-(2-methylpropanoyl)-N-ethylsulphonyl-amino, N-acetyl-N-ethylsulphonyl-amino, N-propionyl-N-ethylsulphonyl-amino, N-n-butyroyl-N-ethylsulphonyl-amino, N-i-butyroyl-N-ethylsulphonyl-amino, N-s-butyroyl-N-ethylsulphonyl-amino, N-t-butyroyl-N-ethylsulphonyl-amino, or represents in each case optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl-, trifluoromethyl-, methoxy-, ethoxy-, n- or i-propoxy-, difluoromethoxy- or trifluoromethoxy-substituted N-phenylcarbonyl-N-methylsulphonyl-amino, N-phenylcarbonyl-N-ethylsulphonyl-amino, N-thienylcarbonyl-N-methylsulphonyl-amino or N-thienylcarbonyl-N-ethylsulphonyl-amino.

[0030] R¹ particularly preferably represents hydrogen, amino, methyl or ethyl.

[0031] R² particularly preferably represents in each case fluorine- and/or chlorine-substituted methyl or ethyl.

[0032] R³ particularly preferably represents hydrogen, fluorine, chlorine, bromine or in each case optionally fluorine- and/or chlorine-substituted methyl or ethyl.

[0033] R⁴ particularly preferably represents hydrogen, fluorine or chlorine.

[0034] R⁵ particularly preferably represents cyano, thiocarbamoyl, chlorine or bromine.

[0035] R⁶ particularly preferably represents nitro, cyano, carboxyl, carbamoyl, thiocarbamoyl, hydroxyl, mercapto, amino, hydroxyamino, aminosulphonyl, fluorine, chlorine, bromine, represents in each case optionally cyano-, carboxyl-, hydroxyl-, methoxy-, ethoxy-, acetyl-, propionyl-, methoxycarbonyl- and/or ethoxycarbonyl, n- or i-propoxycarbonyl-, allyloxycarbonyl- or propargyloxycarbonyl-substituted methyl, ethyl, n- or i-propyl, methoxy, ethoxy, n- or i-propoxy, methylthio, ethylthio, n- or i-propylthio, methylsulphinyl, ethylsulphinyl, methylsulphonyl, ethylsulphonyl, acetyl, propionyl, n- or i-butyroyl, methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl, methylamino, ethylamino, n- or i-propylamino, represents in each case optionally cyano-, carboxyl-, fluorine-, chlorine-, bromine-, methoxycarbonyl- and/or ethoxycarbonyl-substituted ethenyl, propenyl, ethinyl, propinyl, propenyloxy or propinyloxy, represents in each case optionally fluorine- and/or chlorine-, methoxy- or ethoxy-substituted acetylamino, propionylamino, methoxycarbonylamino, ethoxycarbonylamino, methylsulphonylamino, ethylsulphonylamino, n- or i-propylsulphonylamino, n-, i-, s- or t-butylsulphonylamino, N,N-bis-methylsulphonyl-amino, N,N-bis-ethylsulphonylamino, N-ethylsulphonyl-N-methylsulphonyl-amino, N-methylsulphonyl-N-n-propylsulphonyl-amino, N-methylsulphonyl-N-i-propylsulphonyl-amino, N-acetyl-N-methylsulphonyl-amino, N-propionyl-N-methylsulphonyl-amino, N-(2,2-dimethyl-propanoyl)-N-ethylsulphonyl-amino, N-(2-methylpropanoyl)-N-ethylsulphonyl-amino, N-n-butyroyl-N-methylsulphonyl-amino, N-i-butyroyl-N-methylsulphonyl-amino, N-s-butyroyl-N-methylsulphonyl-amino, N-t-butyroyl-N-methylsulphonyl-amino, N-acetyl-N-ethylsulphonyl-amino, N-propionyl-N-ethylsulphonyl-amino, N-n-butyroyl-N-ethylsulphonyl-amino, N-i-butyroyl-N-ethylsulphonyl-amino, N-s-butyroyl-N-ethylsulphonyl-amino, N-t-butyroyl-N-ethylsulphonyl-amino, or represents in each case optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, trifluoromethyl-, methoxy-, ethoxy-, difluoromethoxy- or trifluoromethoxy-substituted N-phenylcarbonyl-N-methylsulphonyl-amino, N-phenylcarbonyl-N-ethylsulphonyl-amino, N-thienylcarbonyl-N-methylsulphonyl-amino or N-thienylcarbonyl-N-ethylsulphonyl-amino.

[0036] Very particularly preferred components of the active compound combinations according to the invention are compounds of the formula (I) in which

[0037] R¹ represents amino,

[0038] R² represents trifluoromethyl,

[0039] R³ represents hydrogen, chlorine or methyl,

[0040] R⁴ represents fluorine,

[0041] R⁵ represents cyano or thiocarbamoyl, and

[0042] R⁶ represents in each case optionally fluorine- and/or chlorine-substituted methylsulphonylamino, ethylsulphonylamino, n- or i-propylsulphonylamino, n-, i-, s- or t-butylsulphonylamino, N,N-bis-methylsulphonyl-amino, N,N-bis-ethylsulphonyl-amino, N-ethylsulphonyl-N-methylsulphonyl-amino, N-methylsulphonyl-N-n-propylsulphonyl-amino, N-methylsulphonyl-N-i-propylsulphonyl-amino, N-acetyl-N-methylsulphonyl-amino, N-propionyl-N-methylsulphonyl-amino, N-(2,2-dimethyl-propanoyl)-N-ethylsulphonyl-amino, N-(2-methylpropanoyl)-N-ethylsulphonyl-amino, N-n-butyroyl-N-methylsulphonyl-amino, N-i-butyroyl-N-methylsulphonyl-amino, N-s-butyroyl-N-methylsulphonyl-amino, N-t-butyroyl-N-methylsulphonyl-amino, N-methoxyacetyl-N-methylsulphonyl-amino, N-acetyl-N-ethylsulphonyl-amino, N-propionyl-N-ethylsulphonyl-amino, N-n-butyroyl-N-ethylsulphonyl-amino, N-i-butyroyl-N-ethylsulphonyl-amino, N-s-butyroyl-N-ethylsulphonyl-amino, N-t-butyroyl-N-ethylsulphonyl-amino, N-methoxyacetyl-N-ethylsulphonyl-amino, or represents in each case optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, Trifluoromethyl-, methoxy-, ethoxy-, difluoromethoxy- or trifluoromethoxy-substituted N-phenylcarbonyl-N-methylsulphonyl-amino, N-phenylcarbonyl-N-ethylsulphonyl-amino, N-thienylcarbonyl-N-methylsulphonyl-amino or N-thienylcarbonyl-N-ethylsulphonyl-amino.

[0043] Other very particularly preferred components of the active compound combinations according to the invention are compounds of the formula (I) in which

[0044] R¹ represents methyl,

[0045] R² represents trifluoromethyl,

[0046] R³ represents hydrogen, chlorine or methyl,

[0047] R⁴ represents fluorine,

[0048] R⁵ represents thiocarbamoyl, and

[0049] R⁶ represents in each case optionally fluorine- and/or chlorine-substituted methylsulphonylamino, ethylsulphonylamino, n- or i-propylsulphonylamino, n-, i-, s- or t-butylsulphonylamino, N,N-bis-methylsulphonyl-amino, N,N-bis-ethylsulphonyl-amino, N-ethylsulphonyl-N-methylsulphonyl-amino, N-methylsulphonyl-N-n-propylsulphonyl-amino, N-methylsulphonyl-N-i-propylsulphonyl-amino, N-acetyl-N-methylsulphonyl-amino, N-propionyl-N-methylsulphonyl-amino, N-(2,2-dimethyl-propanoyl)-N-ethylsulphonyl-amino, N-(2-methylpropanoyl)-N-ethylsulphonyl-amino, N-n-butyroyl-N-methylsulphonyl-amino, N-i-butyroyl-N-methylsulphonyl-amino, N-s-butyroyl-N-methylsulphonyl-amino, N-t-butyroyl-N-methylsulphonyl-amino, N-methoxyacetyl-N-methylsulphonyl-amino, N-acetyl-N-ethylsulphonyl-amino, N-propionyl-N-ethylsulphonyl-amino, N-n-butyroyl-N-ethylsulphonyl-amino, N-i-butyroyl-N-ethylsulphonyl-amino, N-s-butyroyl-N-ethylsulphonyl-amino, N-t-butyroyl-N-ethylsulphonyl-amino, N-methoxyacetyl-N-ethylsulphonyl-amino, or represents in each case optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, trifluoromethyl-, methoxy-, ethoxy-, difluoromethoxy- or trifluoromethoxy-substituted N-phenylcarbonyl-N-methylsulphonyl-amino, N-phenylcarbonyl-N-ethylsulphonyl-amino, N-thienylcarbonyl-N-methylsulphonyl-amino or N-thienylcarbonyl-N-ethylsulphonyl-amino.

[0050] Other very particularly preferred components of the active compound combinations according to the invention are compounds of the formula (I) in which

[0051] R¹ represents amino or methyl,

[0052] R² represents trifluoromethyl,

[0053] R³ represents hydrogen, chlorine or methyl,

[0054] R⁴ represents hydrogen, fluorine or chlorine,

[0055] R⁵ represents cyano, thiocarbamoyl or chlorine, and

[0056] R⁶ represents carboxyl, carbamoyl, thiocarbamoyl, hydroxyl, mercapto, amino, fluorine, chlorine, bromine, represents in each case optionally cyano-, carboxyl-, hydroxyl-, methoxy-, ethoxy-, acetyl-, propionyl-, methoxycarbonyl-, ethoxycarbonyl-, n- or i-propoxycarbonyl-, allyloxycarbonyl- or propargyloxycarbonyl-substituted methyl, ethyl, n- or i-propyl, methoxy, ethoxy, n- or i-propoxy, methylthio, ethylthio, n- or i-propylthio, methylsulphinyl, ethylsulphinyl, methylsulphonyl, ethylsulphonyl, acetyl, propionyl, n- or i-butyroyl, methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl, methylamino, ethylamino, n- or i-propylamino, N-(2,2-dimethyl-propanoyl)-N-ethylsulphonyl-amino, N-(2-methyl-propanoyl)-N-ethylsulphonyl-amino, or represents in each case optionally cyano-, carboxyl-, fluorine-, chlorine-, bromine-, methoxycarbonyl- and/or ethoxycarbonyl-substituted ethenyl, propenyl, ethinyl, propinyl, propenyloxy or propinyloxy.

[0057] Examples of the compounds of the formula (I) which may be mentioned and can be used as mixing partners according to the invention are:

[0058] 5-fluoro-4-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-2-methoxy-benzonitrile

[0059] 5-fluoro-4-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1(2H)-pyrimidinyl)-2-ethoxy-benzonitrile

[0060] 5-fluoro-4-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-2-n-propoxy-benzonitrile

[0061] 5-fluoro-4-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-2-i-propoxy-benzonitrile

[0062] 5-fluoro-4-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-2-n-butoxy-benzonitrile

[0063] 5-fluoro-4-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-2-i-butoxy-benzonitrile

[0064] 5-fluoro-4-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-2-s-butoxy-benzonitrile

[0065] 5-fluoro-4-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-2-allyloxy-benzonitrile

[0066] 5-fluoro-4-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-2-propargyloxy-benzonitrile

[0067] 5-fluoro-4-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-2-[(1-methyl-2-propinyl)-oxy]-benzonitrile

[0068] methyl 2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H)-pyrimidinyl)-benzoate

[0069] ethyl 2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H)-pyrimidinyl)-benzoate

[0070] n-propyl 2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-[(2H)-pyrimidinyl)-benzoate

[0071] i-propyl 2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H)-pyrimidinyl)-benzoate

[0072] [1,1-dimethyl-2-oxo-2-(2-propenyloxy)]-ethyl] 2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H)-pyrimidinyl)-benzoate

[0073] 2-(methylsulphonylamino)-5-fluoro-4-[3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl]-benzenecarbothioamide

[0074] 2-(ethylsulphonylamino)-5-fluoro-4-[3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl]-benzenecarbothioamide

[0075] 2-(n-propylsulphonylamino)-5-fluoro-4-[3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl]-benzenecarbothioamide

[0076] 2-(i-propylsulphonylamino)-5-fluoro-4-[3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl]-benzenecarbothioamide

[0077] 2-(n-butylsulphonylamino)-5-fluoro-4-[3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl]-benzenecarbothioamide

[0078] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(acetyl)-1-methanesulphonamide

[0079] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(methylsulphonyl)-1-methanesulphonamide

[0080] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(ethylsulphonyl)-1-methanesulphonamide

[0081] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(ethylsulphonyl)-1-ethanesulphonamide

[0082] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(n-propylsulphonyl)-1-methanesulphonamide

[0083] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1(2H)-pyrimidinyl)-phenyl]-N-(i-propylsulphonyl)-1-methanesulphonamide

[0084] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(acetyl)-1-methanesulphonamide

[0085] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(acetyl)-1-ethanesulphonamide

[0086] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(propanoyl)-1-methanesulphonamide

[0087] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(propanoyl)-1-ethanesulphonamide

[0088] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1(2H)-pyrimidinyl)-phenyl]-N-(2-methyl-propanoyl)-1-methanesulphonamide

[0089] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(2-methyl-propanoyl)-1-ethanesulphonamide

[0090] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1(2H)-pyrimidinyl)-phenyl]-N-(butanoyl)-1-methanesulphonamide

[0091] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1(2H)-pyrimidinyl)-phenyl]-N-(butanoyl)-1-ethanesulphonamide

[0092] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(2-methyl-butanoyl)-1-methanesulphonamide

[0093] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(2-methyl-butanoyl)-1-ethanesulphonamide

[0094] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1(2H)-pyrimidinyl)-phenyl]-N-(2,2-dimethyl-propanoyl)-1-methanesulphonamide

[0095] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(2,2-dimethyl-propanoyl)-1-ethanesulphonamide

[0096] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(methoxyacetyl)-1-methanesulphonamide

[0097] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(methoxyacetyl)-1-ethanesulphonamide

[0098] N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(4-methoxy-benzoyl)-ethanesulphonamide

[0099] N-[5-(3-amino-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-2-cyano-4-fluoro-phenyl]-N-benzoyl-1-methanesulphonamide

[0100] N-[5-(3-amino-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-2-cyano-4-fluoro-phenyl]-N-benzoyl-1-ethanesulphonamide

[0101] N-[5-(3-amino-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-2-cyano-4-fluoro-phenyl]-N-(4-methoxy-benzoyl)-1-methanesulphonamide

[0102] N-[5-(3-amino-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-2-cyano-4-fluoro-phenyl]-N-(2-thienyl-carbonyl)-1-methanesulphonamide

[0103] N-[5-(3-amino-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1(2H)-pyrimidinyl)-2-cyano-4-fluoro-phenyl]-N-(2-thienyl-carbonyl)-1-ethanesulphonamide

[0104] Particular emphasis is given to the compound [1,1-dimethyl-2-oxo-2-(2-propenyloxy)]-ethyl 2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1(2H)-pyrimidinyl)-benzoate (I-1)—CAS-Reg.No.: 134605-64-4—as mixing component of the formula (I) (WO 91/00278).

[0105] Particular emphasis is likewise given to the compound 5-fluoro-4-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-2-[(1-methyl-2-propinyl)-oxy]-benzonitrile (I-2)—CAS-Reg.No.: 186605-50-5—as mixing component of the formula (I) (WO 97/01541).

[0106] Particular emphasis is likewise given to the compound N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(2,2-dimethyl-propanoyl)-1-ethanesulphonamide (I-3)—according to Chem. Abstracts also to be referred to as N-[2-cyano-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H)-pyrimidinyl)-4-fluoro-phenyl]-N-ethylsulphonyl-2,2-dimethyl-propanamide (CAS-Reg.-No.: 232262-67-8)—as mixing component of the formula (I) (WO 95/29168).

[0107] Particular emphasis is likewise given to the compound N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(4-methoxy-benzoyl)-ethanesulphonamide (I-4)—according to Chem. Abstracts also to be referred to as N-[2-cyano-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H)-pyrimidinyl)-4-fluoro-phenyl]-N-ethylsulphonyl-4-methoxy-benzamide (CAS-Reg.-No.: 184293-08-1)—as mixing component of the formula (I) (WO 96/35679).

[0108] Particular emphasis is likewise given to the compound N-[5-(3-amino-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-2-cyano-4-fluoro-phenyl]-N-(2-thienyl-carbonyl)-1-ethanesulphonamide (I-5)—according to Chem. Abstracts also to be referred to as N-[2-cyano-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1(2H)-pyrimidinyl)-4-fluoro-phenyl]-N-ethylsulphonyl-2-thiophene-carboxamide-as mixing component of the formula (I) (WO 96/35679).

[0109] Particular emphasis is likewise given to the compound 2-(ethylsulphonylamino)-5-fluoro-4-[3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl]-benzenecarbothioamide (I-6)—according to Chem. Abstracts also to be referred to as 4-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H)-pyrimidinyl)-2-ethylsulphonylamino-5-fluoro-benzenecarbothioamide (CAS-Reg.-No.: 173980-09-1)—as mixing component of the formula (I) (WO 95/30661).

[0110] The compounds of the formula (I) are described in the patent applications or patents mentioned above for the N-aryl-uracils.

[0111] According to their chemical structure, the active compounds of Group 2 can be classified under the following classes of active compounds.

[0112] Amides (for example isoxaben, picolinafen, propanil), arylheterocycles (for example azafenidin, benzfendizone, butafenacil-allyl, carfentrazone-ethyl, cinidon-ethyl, fluazolate, flumiclorac-pentyl, flumioxazin, flupropacil, fluthiacet-methyl, oxadiazon, oxadiargyl, profluazol, pyraflufen-ethyl, pyridate, pyridafol, sulfentrazone, thidiazimin, 4-[4,5-dihydro-4-methyl-5-oxo-(3-trifluoromethyl)-1H-1,2,4-triazol-1-yl]-2-[(ethylsulphonyl)amino]-5-fluoro-benzenecarbothioamide), aryloxyphenoxy-propionates (for example clodinafop-propargyl, cyhalofop-butyl, diclofop-methyl, fenoxaprop-P-ethyl, fluazifop-P-butyl, haloxyfop-R-methyl, quizalofop-P-ethyl), carboxylic acid derivatives (for example clopyralid, dicamba, fluroxypyr, picloram, triclopyr), benzothiadiazoles (for example bentazon), chloroacetamides (for example acetochlor, alachlor, butachlor, (S—) dimethenamid, metazachlor, metolachlor, pretilachlor, propachlor, propisochlor), cyclohexanediones (for example butroxydim, clefoxydim, cycloxydim, sethoxydim, tralkoxydim), dinitroanilines (for example benfluralin, ethalfluralin, oryzalin, pendimethalin, trifluralin), diphenyl ethers (for example acifluorfen-sodium, aclonifen, bifenox, fluoroglycofen-ethyl, fomesafen, lactofen, oxyfluorfen), ureas (for example chlortoluron, diuron, isoproturon, linuron, metobromuron, metoxuron), imidazolinones (for example imazamethabenz-methyl, imazamox, imazaquin, imazethapyr), isoxazoles (for example isoxaflutole), nicotinanilides (for example diflufenican), nitriles (for example bromoxynil, ioxynil), organophosphorus compounds (for example glufosinate-ammonium, glyphosate-iso-propylammonium, sulfosate), oxyacetamides (for example flufenacet, mefenacet), phenoxycarboxylic acid derivatives (for example 2,4-D, dichlorprop-P, MCPA, MCPB, mecoprop), pyrazoles (for example pyrazolate, pyrazoxyfen), pyridazinones (for example norflurazon), pyridines (for example dithiopyr, thiazopyr), pyrimidinyl(thio)benzoates (for example bispyribac, pyribenzoxim, pyrithiobac, pyriminobac), sulphonylureas (for example amidosulfuron, azimsulfuron, bensulfuron-methyl, chlorimuron-ethyl, chlorsulfuron, cinosulfuron, cyclosulfamuron, ethoxysulfuron, flupyrsulfuron-methyl-sodium, foramsulfuron, iodosulfuron-methyl-sodium, imazosulfuron, metsulfuron-methyl, nicosulfuron, oxasulfuron, primisulfuron-methyl, prosulfuron, pyrazosulfuron-ethyl, rimsulfuron, sulfometuron-methyl, sulfosulfuron, thifensulfuron-methyl, triasulfuron, tribenuron-methyl, trifloxysulfuron, triflusulfuron-methyl, tritosulfuron), tetrazolinones (for example fentrazamide), thiocarbamates (for example butylate, dimepiperate, EPTC, esprocarb, molinate, orbencarb, prosulfocarb, triallate), triazines (for example ametryn, atrazine, cyanazine, dimexyflam, simazin, terbuthylazine, terbutryn), triazinones (for example hexazinone, metamitron, metribuzin), triazoles (for example amitrole), triazolinones (for example amicarbazone, flucarbazone-sodium, propoxycarbazone-sodium), triazolo-pyrimidines (for example cloransulam-methyl, diclosulam, florasulam, flumetsulam, metosulam), triketones (for example mesotrione, sulcotrione), uracils (for example bromacil).

[0113] Mixing components from the active compounds of Group 2 which are particularly emphasized are:

[0114] acetochlor, alachlor, amicarbazone, amitrole, atrazine, bromacil, carfentrazone-ethyl, chlorimuron-ethyl, clodinafop-propargyl, cyanazine, diclosulam, dimethenamid, S-dimethenamid, diuron, EPTC, fenoxaprop-P-ethyl, fentrazamide, flucarbazone-sodium, flufenacet, flumetsulam, glufosinate-ammonium, glyphosate-isopropylammonium, imazamox, imazaquin, imazethapyr, isoxaflutole, mesotrione, metolachlor, S-metolachlor, metosulam, metribuzin, nicosulfuron, norflurazon, pendimethalin, propoxycarbazone-sodium, rimsulfuron, simazin, sulfometuron-methyl, sulcotrione, sulfentrazone, sulfosate, terbuthylazine, thifensulfuron-methyl, trifluralin, 4-[4,5-dihydro-4-methyl-5-oxo-(3-trifluoromethyl)-1H-1,2,4-triazol-1-yl]-2-[(ethylsulphonyl)amino]-5-fluoro-benzenecarbothioamide.

[0115] According to their chemical structure, the particularly emphasized active compounds of the Group 2 can be classified under the following classes of active compounds:

[0116] Arylheterocycles (for example carfentrazone-ethyl, sulfentrazone, 4-[4,5-dihydro-4-methyl-5-oxo-(3-trifluoromethyl)-1H-1,2,4-triazol-1-yl]-2-[(ethylsulphonyl)-amino]-5-fluoro-benzenecarbothioamide), chloroacetamides (for example acetochlor, alachlor, dimethenamid, S-dimethenamid, metolachlor, S-metolachlor), dinitroanilines (for example pendimethalin, trifluralin), ureas (for example diuron), imidazolinones (for example imazamox, imazaquin, imazethapyr), organophosphorus compounds (for example glufosinate, glyphosate, sulfosate), oxyacetamides (for example flufenacet), pyridazinones (for example norflurazon), sulfonylureas (for example chlorimuron-ethyl, nicosulfuron, rimsulfuron, sulfometuron-methyl, thifensulfuron-methyl), tetrazolinones (for example fentrazamide), triazines (for example atrazine, cyanazine, simazine, terbuthylazine), triazinones (for example metribuzin), triazolinones (for example amicarbazone, flucarbazone-sodium, propoxycarbazone-sodium), triazolopyrimidines (for example diclosulam, florasulam, metosulam), triketones (for example mesotrione, sulcotrione), uracils (for example bromacil).

[0117] The compositions according to the invention may comprise one or two active compounds of Group 1 and one active compound of Group 3.

[0118] The compositions according to the invention preferably comprise one or two active compounds of Group 1, one to three active compounds of Group 2 and optionally one active compound of Group 3.

[0119] In particular, the compositions according to the invention comprise one active compound of Group 1, one or two active compounds of Group 2 and optionally one active compound of Group 3.

[0120] Examples of combinations according to the invention comprising in each case one active compound of Group 1 and two active compounds of Group 2 (preferably selected from the group of the photosynthesis inhibitors on the one hand and the group of the acetyl-CoA-carboxylase inhibitors on the other hand)—or in each case one active compound of Group 1, two active compounds of Group 2 and one compound of Group 3—are listed in Table 1 below. TABLE 1 Active Second active compound of compound First active Group 2 (if appropriate + additional of compound active compound of Group 1 of Group 2 Group 3) I-1 amicarbazone clodinafop-propargyl I-1 amicarbazone clodinafop-propargyl + cloquintocet-mexyl I-1 amicarbazone fenoxaprop-P-ethyl I-1 amicarbazone fenoxaprop-P-ethyl + mefenpyr-diethyl I-1 amicarbazone flucarbazone-sodium I-1 amicarbazone propoxycarbazone-sodium I-1 amicarbazone alachlor I-1 amicarbazone dimethenamid I-1 amicarbazone S-dimethenamid I-1 amicarbazone metolachlor I-1 amicarbazone metolachlor + benoxacor I-1 amicarbazone S-metolachlor I-1 amicarbazone S-metolachlor + benoxacor I-1 amicarbazone acetochlor I-1 amicarbazone acetochlor + dichlormid I-1 amicarbazone acetochlor + R-29148 I-1 amicarbazone flufenacet I-1 atrazine clodinafop-propargyl I-1 atrazine clodinafop-propargyl + cloquintocet-mexyl I-1 atrazine fenoxaprop-P-ethyl I-1 atrazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-1 atrazine flucarbazone-sodium I-1 atrazine propoxycarbazone-sodium I-1 atrazine alachlor I-1 atrazine dimethenamid I-1 atrazine S-dimethenamid I-1 atrazine acetochlor I-1 atrazine acetochlor + dichlormid I-1 atrazine acetochlor + R-29148 I-1 atrazine flufenacet I-1 atrazine metolachlor I-1 atrazine metolachlor + benoxacor I-1 atrazine S-metolachlor I-1 atrazine S-metolachlor + benoxacor I-1 metribuzin clodinafop-propargyl I-1 metribuzin clodinafop-propargyl + cloquintocet-mexyl I-1 metribuzin fenoxaprop-P-ethyl I-1 metribuzin fenoxaprop-P-ethyl + mefenpyr-diethyl I-1 metribuzin flucarbazone-sodium I-1 metribuzin propoxycarbazone-sodium I-1 metribuzin alachlor I-1 metribuzin dimethenamid I-1 metribuzin S-dimethenamid I-1 metribuzin metolachlor I-1 metribuzin metolachlor + benoxacor I-1 metribuzin metolachlor I-1 metribuzin metolachlor + benoxacor I-1 metribuzin acetochlor I-1 metribuzin acetochlor + dichlormid I-1 metribuzin acetochlor + R-29148 I-1 metribuzin acetochlor + furilazone I-1 metribuzin flufenacet I-1 terbuthylazine clodinafop-propargyl I-1 terbuthylazine clodinafop-propargyl + cloquintocet-mexyl I-1 terbuthylazine fenoxaprop-P-ethyl I-1 terbuthylazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-1 terbuthylazine flucarbazone-sodium I-1 terbuthylazine propoxycarbazone-sodium I-1 terbuthylazine alachlor I-1 terbuthylazine dimethenamid I-1 terbuthylazine S-dimethenamid I-1 terbuthylazine acetochlor I-1 terbuthylazine acetochlor + dichlormid I-1 terbuthylazine acetochlor + R-29148 I-1 terbuthylazine acetochlor + furilazole I-1 terbuthylazine flufenacet I-1 simazine clodinafop-propargyl I-1 simazine clodinafop-propargyl + cloquintocet-mexyl I-1 simazine fenoxaprop-P-ethyl I-1 simazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-1 simazine flucarbazone-sodium I-1 simazine propoxycarbazone-sodium I-1 simazine alachlor I-1 simazine dimethenamid I-1 simazine S-dimethenamid I-1 simazine metolachlor I-1 simazine metolachlor + benoxacor I-1 simazine S-metolachlor I-1 simazine S-metolachlor + benoxacor I-1 simazine acetochlor I-1 simazine acetochlor + dichlormid I-1 simazine acetochlor + R-29148 I-1 simazine acetochlor + furilazole I-1 simazine flufenacet I-1 cyanazine clodinafop-propargyl I-1 cyanazine clodinafop-propargyl + cloquintocet-mexyl I-1 cyanazine fenoxaprop-P-ethyl I-1 cyanazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-1 cyanazine flucarbazone-sodium I-1 cyanazine propoxycarbazone-sodium I-1 cyanazine alachlor I-1 cyanazine dimethenamid I-1 cyanazine S-dimethenamid I-1 cyanazine metolachlor I-1 cyanazine metolachlor + benoxacor I-1 cyanazine S-metolachlor I-1 cyanazine S-metolachlor + benoxacor I-1 cyanazine acetochlor I-1 cyanazine acetochlor + dichlormid I-1 cyanazine acetochlor + R-29148 I-1 cyanazine acetochlor + furilazole I-1 cyanazine flufenacet I-2 amicarbazone clodinafop-propargyl I-2 amicarbazone clodinafop-propargyl + cloquintocet-mexyl I-2 amicarbazone fenoxaprop-P-ethyl I-2 amicarbazone fenoxaprop-P-ethyl + mefenpyr-diethyl I-2 amicarbazone flucarbazone-sodium I-2 amicarbazone propoxycarbazone-sodium I-2 amicarbazone alachlor I-2 amicarbazone dimethenamid I-2 amicarbazone S-dimethenamid I-2 amicarbazone metolachlor I-2 amicarbazone metolachlor + benoxacor I-2 amicarbazone S-metolachlor I-2 amicarbazone S-metolachlor + benoxacor I-2 amicarbazone acetochlor I-2 amicarbazone acetochlor + dichlormid I-2 amicarbazone acetochlor + R-29148 I-2 amicarbazone acetochlor + furilazole I-2 amicarbazone flufenacet I-2 atrazine clodinafop-propargyl I-2 atrazine clodinafop-propargyl + cloquintocet-mexyl I-2 atrazine fenoxaprop-P-ethyl I-2 atrazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-2 atrazine flucarbazone-sodium I-2 atrazine propoxycarbazone-sodium I-2 atrazine alachlor I-2 atrazine dimethenamid I-2 atrazine S-dimethenamid I-2 atrazine metolachlor I-2 atrazine metolachlor + benoxacor I-2 atrazine S-metolachlor I-2 atrazine S-metolachlor + benoxacor I-2 atrazine acetochlor I-2 atrazine acetochlor + dichlormid I-2 atrazine acetochlor + R-29148 I-2 atrazine acetochlor + furilazole I-2 atrazine flufenacet I-2 metribuzin clodinafop-propargyl I-2 metribuzin clodinafop-propargyl + cloquintocet-mexyl I-2 metribuzin fenoxaprop-P-ethyl I-2 metribuzin fenoxaprop-P-ethyl + mefenpyr-diethyl I-2 metribuzin flucarbazone-sodium I-2 metribuzin propoxycarbazone-sodium I-2 metribuzin alachlor I-2 metribuzin dimethenamid I-2 metribuzin S-dimethenamid I-2 metribuzin metolachlor I-2 metribuzin metolachlor + benoxacor I-2 metribuzin metolachlor I-2 metribuzin metolachlor + benoxacor I-2 metribuzin acetochlor I-2 metribuzin acetochlor + dichlormid I-2 metribuzin acetochlor + R-29148 I-2 metribuzin acetochlor + furilazole I-2 metribuzin flufenacet I-2 terbuthylazine clodinafop-propargyl I-2 terbuthylazine clodinafop-propargyl + cloquintocet-mexyl I-2 terbuthylazine fenoxaprop-P-ethyl I-2 terbuthylazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-2 terbuthylazine flucarbazone-sodium I-2 terbuthylazine propoxycarbazone-sodium I-2 terbuthylazine alachlor I-2 terbuthylazine dimethenamid I-2 terbuthylazine S-dimethenamid I-2 terbuthylazine metolachlor I-2 terbuthylazine metolachlor + benoxacor I-2 terbuthylazine S-metolachlor I-2 terbuthylazine S-metolachlor + benoxacor I-2 terbuthylazine acetochlor I-2 terbuthylazine acetochlor + dichlormid I-2 terbuthylazine acetochlor + R-29148 I-2 terbuthylazine acetochlor + furilazole I-2 terbuthylazine flufenacet I-2 simazine clodinafop-propargyl I-2 simazine clodinafop-propargyl + cloquintocet-mexyl I-2 simazine fenoxaprop-P-ethyl I-2 simazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-2 simazine flucarbazone-sodium I-2 simazine propoxycarbazone-sodium I-2 simazine alachlor I-2 simazine dimethenamid I-2 simazine S-dimethenamid I-2 simazine metolachlor I-2 simazine metolachlor + benoxacor I-2 simazine S-metolachlor I-2 simazine S-metolachlor + benoxacor I-2 simazine acetochlor I-2 simazine acetochlor + dichlormid I-2 simazine acetochlor + R-29148 I-2 simazine acetochlor + furilazole I-2 simazine flufenacet I-2 cyanazine clodinafop-propargyl I-2 cyanazine clodinafop-propargyl + cloquintocet-mexyl I-2 cyanazine fenoxaprop-P-ethyl I-2 cyanazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-2 cyanazine flucarbazone-sodium I-2 cyanazine propoxycarbazone-sodium I-2 cyanazine alachlor I-2 cyanazine dimethenamid I-2 cyanazine S-dimethenamid I-2 cyanazine metolachlor I-2 cyanazine metolachlor + benoxacor I-2 cyanazine S-metolachlor I-2 cyanazine S-metolachlor + benoxacor I-2 cyanazine acetochlor I-2 cyanazine acetochlor + dichlormid I-2 cyanazine acetochlor + R-29148 I-2 cyanazine acetochlor + furilazole I-2 cyanazine flufenacet I-3 amicarbazone clodinafop-propargyl I-3 amicarbazone clodinafop-propargyl + cloquintocet-mexyl I-3 amicarbazone fenoxaprop-P-ethyl I-3 amicarbazone fenoxaprop-P-ethyl + mefenpyr-diethyl I-3 amicarbazone flucarbazone-sodium I-3 amicarbazone propoxycarbazone-sodium I-3 amicarbazone alachlor I-3 amicarbazone dimethenamid I-3 amicarbazone S-dimethenamid I-3 amicarbazone metolachlor I-3 amicarbazone metolachlor + benoxacor I-3 amicarbazone S-metolachlor I-3 amicarbazone S-metolachlor + benoxacor I-3 amicarbazone acetochlor I-3 amicarbazone acetochlor + dichlormid I-3 amicarbazone acetochlor + R-29148 I-3 amicarbazone acetochlor + furilazole I-3 amicarbazone flufenacet I-3 atrazine clodinafop-propargyl I-3 atrazine clodinafop-propargyl + cloquintocet-mexyl I-3 atrazine fenoxaprop-P-ethyl I-3 atrazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-3 atrazine flucarbazone-sodium I-3 atrazine propoxycarbazone-sodium I-3 atrazine alachlor I-3 atrazine dimethenamid I-3 atrazine S-dimethenamid I-3 atrazine metolachlor I-3 atrazine metolachlor + benoxacor I-3 atrazine S-metolachlor I-3 atrazine S-metolachlor + benoxacor I-3 atrazine acetochlor I-3 atrazine acetochlor + dichlormid I-3 atrazine acetochlor + R-29148 I-3 atrazine acetochlor + furilazole I-3 atrazine flufenacet I-3 metribuzin clodinafop-propargyl I-3 metribuzin clodinafop-propargyl + cloquintocet-mexyl I-3 metribuzin fenoxaprop-P-ethyl I-3 metribuzin fenoxaprop-P-ethyl + mefenpyr-diethyl I-3 metribuzin flucarbazone-sodium I-3 metribuzin propoxycarbazone-sodium I-3 metribuzin alachlor I-3 metribuzin dimethenamid I-3 metribuzin S-dimethenamid I-3 metribuzin metolachlor I-3 metribuzin metolachlor + benoxacor I-3 metribuzin metolachlor I-3 metribuzin metolachlor + benoxacor I-3 metribuzin acetochlor I-3 metribuzin acetochlor + dichlormid I-3 metribuzin acetochlor + R-29148 I-3 metribuzin acetochlor + furilazole I-3 metribuzin flufenacet I-3 terbuthylazine clodinafop-propargyl I-3 terbuthylazine clodinafop-propargyl + cloquintocet-mexyl I-3 terbuthylazine fenoxaprop-P-ethyl I-3 terbuthylazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-3 terbuthylazine flucarbazone-sodium I-3 terbuthylazine propoxycarbazone-sodium I-3 terbuthylazine alachlor I-3 terbuthylazine dimethenamid I-3 terbuthylazine S-dimethenamid I-3 terbuthylazine metolachlor I-3 terbuthylazine metolachlor + benoxacor I-3 terbuthylazine S-metolachlor I-3 terbuthylazine S-metolachlor + benoxacor I-3 terbuthylazine acetochlor I-3 terbuthylazine acetochlor + dichlormid I-3 terbuthylazine acetochlor + R-29148 I-3 terbuthylazine flufenacet I-3 terbuthylazine acetochlor + furilazole I-3 simazine clodinafop-propargyl I-3 simazine clodinafop-propargyl + cloquintocet-mexyl I-3 simazine fenoxaprop-P-ethyl I-3 simazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-3 simazine flucarbazone-sodium I-3 simazine propoxycarbazone-sodium I-3 simazine alachlor I-3 simazine dimethenamid I-3 simazine S-dimethenamid I-3 simazine metolachlor I-3 simazine metolachlor + benoxacor I-3 simazine S-metolachlor I-3 simazine S-metolachlor + benoxacor I-3 simazine acetochlor I-3 simazine acetochlor + dichlormid I-3 simazine acetochlor + R-29148 I-3 simazine acetochlor + furilazole I-3 simazine flufenacet I-3 cyanazine clodinafop-propargyl I-3 cyanazine clodinafop-propargyl + cloquintocet-mexyl I-3 cyanazine fenoxaprop-P-ethyl I-3 cyanazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-3 cyanazine flucarbazone-sodium I-3 cyanazine propoxycarbazone-sodium I-3 cyanazine alachlor I-3 cyanazine dimethenamid I-3 cyanazine S-dimethenamid I-3 cyanazine metolachlor I-3 cyanazine metolachlor + benoxacor I-3 cyanazine S-metolachlor I-3 cyanazine S-metolachlor + benoxacor I-3 cyanazine acetochlor I-3 cyanazine acetochlor + dichlormid I-3 cyanazine acetochlor + R-29148 I-3 cyanazine acetochlor + furilazole I-3 cyanazine flufenacet I-4 amicarbazone clodinafop-propargyl I-4 amicarbazone clodinafop-propargyl + cloquintocet-mexyl I-4 amicarbazone fenoxaprop-P-ethyl I-4 amicarbazone fenoxaprop-P-ethyl + mefenpyr-diethyl I-4 amicarbazone flucarbazone-sodium I-4 amicarbazone propoxycarbazone-sodium I-4 amicarbazone alachlor I-4 amicarbazone dimethenamid I-4 amicarbazone S-dimethenamid I-4 amicarbazone metolachlor I-4 amicarbazone metolachlor + benoxacor I-4 amicarbazone S-metolachlor I-4 amicarbazone S-metolachlor + benoxacor I-4 amicarbazone acetochlor I-4 amicarbazone acetochlor + dichlormid I-4 amicarbazone acetochlor + R-29148 I-4 amicarbazone acetochlor + furilazole I-4 amicarbazone flufenacet I-4 atrazine clodinafop-propargyl I-4 atrazine clodinafop-propargyl + cloquintocet-mexyl I-4 atrazine fenoxaprop-P-ethyl I-4 atrazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-4 atrazine flucarbazone-sodium I-4 atrazine propoxycarbazone-sodium I-4 atrazine alachlor I-4 atrazine dimethenamid I-4 atrazine S-dimethenamid I-4 atrazine metolachlor I-4 atrazine metolachlor + benoxacor I-4 atrazine S-metolachlor I-4 atrazine S-metolachlor + benoxacor I-4 atrazine acetochlor I-4 atrazine acetochlor + dichlormid I-4 atrazine acetochlor + R-29148 I-4 atrazine acetochlor + furilazole I-4 atrazine flufenacet I-4 metribuzin clodinafop-propargyl I-4 metribuzin clodinafop-propargyl + cloquintocet-mexyl I-4 metribuzin fenoxaprop-P-ethyl I-4 metribuzin fenoxaprop-P-ethyl + mefenpyr-diethyl I-4 metribuzin flucarbazone-sodium I-4 metribuzin propoxycarbazone-sodium I-4 metribuzin alachlor I-4 metribuzin dimethenamid I-4 metribuzin S-dimethenamid I-4 metribuzin metolachlor I-4 metribuzin metolachlor + benoxacor I-4 metribuzin metolachlor I-4 metribuzin metolachlor + benoxacor I-4 metribuzin acetochlor I-4 metribuzin acetochlor + dichlormid I-4 metribuzin acetochlor + R-29148 I-4 metribuzin acetochlor + furilazole I-4 metribuzin flufenacet I-4 terbuthylazine clodinafop-propargyl I-4 terbuthylazine clodinafop-propargyl + cloquintocet-mexyl I-4 terbuthylazine fenoxaprop-P-ethyl I-4 terbuthylazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-4 terbuthylazine flucarbazone-sodium I-4 terbuthylazine propoxycarbazone-sodium I-4 terbuthylazine alachlor I-4 terbuthylazine dimethenamid I-4 terbuthylazine S-dimethenamid I-4 terbuthylazine metolachlor I-4 terbuthylazine metolachlor + benoxacor I-4 terbuthylazine S-metolachlor I-4 terbuthylazine S-metolachlor + benoxacor I-4 terbuthylazine acetochlor I-4 terbuthylazine acetochlor + dichlormid I-4 terbuthylazine acetochlor + R-29148 I-4 terbuthylazine acetochlor + furilazole I-4 terbuthylazine flufenacet I-4 simazine clodinafop-propargyl I-4 simazine clodinafop-propargyl + cloquintocet-mexyl I-4 simazine fenoxaprop-P-ethyl I-4 simazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-4 simazine flucarbazone-sodium I-4 simazine propoxycarbazone-sodium I-4 simazine alachlor I-4 simazine dimethenamid I-4 simazine S-dimethenamid I-4 simazine metolachlor I-4 simazine metolachlor + benoxacor I-4 simazine S-metolachlor I-4 simazine S-metolachlor + benoxacor I-4 simazine acetochlor I-4 simazine acetochlor + dichlormid I-4 simazine acetochlor + R-29148 I-4 simazine acetochlor + furilazole I-4 simazine flufenacet I-4 cyanazine clodinafop-propargyl I-4 cyanazine clodinafop-propargyl + cloquintocet-mexyl I-4 cyanazine fenoxaprop-P-ethyl I-4 cyanazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-4 cyanazine flucarbazone-sodium I-4 cyanazine propoxycarbazone-sodium I-4 cyanazine alachlor I-4 cyanazine dimethenamid I-4 cyanazine S-dimethenamid I-4 cyanazine metolachlor I-4 cyanazine metolachlor + benoxacor I-4 cyanazine S-metolachlor I-4 cyanazine S-metolachlor + benoxacor I-4 cyanazine acetochlor I-4 cyanazine acetochlor + dichlormid I-4 cyanazine acetochlor + R-29148 I-4 cyanazine acetochlor + furilazole I-4 cyanazine flufenacet I-5 amicarbazone clodinafop-propargyl I-5 amicarbazone clodinafop-propargyl + cloquintocet-mexyl I-5 amicarbazone fenoxaprop-P-ethyl I-5 amicarbazone fenoxaprop-P-ethyl + mefenpyr-diethyl I-5 amicarbazone flucarbazone-sodium I-5 amicarbazone propoxycarbazone-sodium I-5 amicarbazone alachlor I-5 amicarbazone dimethenamid I-5 amicarbazone S-dimethenamid I-5 amicarbazone metolachlor I-5 amicarbazone metolachlor + benoxacor I-5 amicarbazone S-metolachlor I-5 amicarbazone S-metolachlor + benoxacor I-5 amicarbazone acetochlor I-5 amicarbazone acetochlor + dichlormid I-5 amicarbazone acetochlor + R-29148 I-5 amicarbazone acetochlor + furilazole I-5 amicarbazone flufenacet I-5 atrazine clodinafop-propargyl I-5 atrazine clodinafop-propargyl + cloquintocet-mexyl I-5 atrazine fenoxaprop-P-ethyl I-5 atrazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-5 atrazine flucarbazone-sodium I-5 atrazine propoxycarbazone-sodium I-5 atrazine alachlor I-5 atrazine dimethenamid I-5 atrazine S-dimethenamid I-5 atrazine metolachlor I-5 atrazine metolachlor + benoxacor I-5 atrazine S-metolachlor I-5 atrazine S-metolachlor + benoxacor I-5 atrazine acetochlor I-5 atrazine acetochlor + dichlormid I-5 atrazine acetochlor + R-29148 I-5 atrazine acetochlor + furilazole I-5 atrazine flufenacet I-5 metribuzin clodinafop-propargyl I-5 metribuzin clodinafop-propargyl + cloquintocet-mexyl I-5 metribuzin fenoxaprop-P-ethyl I-5 metribuzin fenoxaprop-P-ethyl + mefenpyr-diethyl I-5 metribuzin flucarbazone-sodium I-5 metribuzin propoxycarbazone-sodium I-5 metribuzin alachlor I-5 metribuzin dimethenamid I-5 metribuzin S-dimethenamid I-5 metribuzin metolachlor I-5 metribuzin metolachlor + benoxacor I-5 metribuzin metolachlor I-5 metribuzin metolachlor + benoxacor I-5 metribuzin acetochlor I-5 metribuzin acetochlor + dichlormid I-5 metribuzin acetochlor + R-29148 I-5 metribuzin acetochlor + furilazole I-5 metribuzin flufenacet I-5 terbuthylazine clodinafop-propargyl I-5 terbuthylazine clodinafop-propargyl + cloquintocet-mexyl I-5 terbuthylazine fenoxaprop-P-ethyl I-5 terbuthylazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-5 terbuthylazine flucarbazone-sodium I-5 terbuthylazine propoxycarbazone-sodium I-5 terbuthylazine alachlor I-5 terbuthylazine dimethenamid I-5 terbuthylazine S-dimethenamid I-5 terbuthylazine metolachlor I-5 terbuthylazine metolachlor + benoxacor I-5 terbuthylazine S-metolachlor I-5 terbuthylazine S-metolachlor + benoxacor I-5 terbuthylazine acetochlor I-5 terbuthylazine acetochlor + dichlormid I-5 terbuthylazine acetochlor + R-29148 I-5 terbuthylazine acetochlor + furilazole I-5 terbuthylazine flufenacet I-5 simazine clodinafop-propargyl I-5 simazine clodinafop-propargyl + cloquintocet-mexyl I-5 simazine fenoxaprop-P-ethyl I-5 simazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-5 simazine flucarbazone-sodium I-5 simazine propoxycarbazone-sodium I-5 simazine alachlor I-5 simazine dimethenamid I-5 simazine S-dimethenamid I-5 simazine metolachlor I-5 simazine metolachlor + benoxacor I-5 simazine S-metolachlor I-5 simazine S-metolachlor + benoxacor I-5 simazine acetochlor I-5 simazine acetochlor + dichlormid I-5 simazine acetochlor + R-29148 I-5 simazine acetochlor + furilazole I-5 simazine flufenacet I-5 cyanazine clodinafop-propargyl I-5 cyanazine clodinafop-propargyl + cloquintocet-mexyl I-5 cyanazine fenoxaprop-P-ethyl I-5 cyanazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-5 cyanazine flucarbazone-sodium I-5 cyanazine propoxycarbazone-sodium I-5 cyanazine alachlor I-5 cyanazine dimethenamid I-5 cyanazine S-dimethenamid I-5 cyanazine metolachlor I-5 cyanazine metolachlor + benoxacor I-5 cyanazine S-metolachlor I-5 cyanazine S-metolachlor + benoxacor I-5 cyanazine acetochlor I-5 cyanazine acetochlor + dichlormid I-5 cyanazine acetochlor + R-29148 I-5 cyanazine acetochlor + furilazole I-5 cyanazine flufenacet I-6 amicarbazone clodinafop-propargyl I-6 amicarbazone clodinafop-propargyl + cloquintocet-mexyl I-6 amicarbazone fenoxaprop-P-ethyl I-6 amicarbazone fenoxaprop-P-ethyl + mefenpyr-diethyl I-6 amicarbazone flucarbazone-sodium I-6 amicarbazone propoxycarbazone-sodium I-6 amicarbazone alachlor I-6 amicarbazone dimethenamid I-6 amicarbazone S-dimethenamid I-6 amicarbazone metolachlor I-6 amicarbazone metolachlor + benoxacor I-6 amicarbazone S-metolachlor I-6 amicarbazone S-metolachlor + benoxacor I-6 amicarbazone acetochlor I-6 amicarbazone acetochlor + dichlormid I-6 amicarbazone acetochlor + R-29148 I-6 amicarbazone acetochlor + furilazole I-6 amicarbazone flufenacet I-6 atrazine clodinafop-propargyl I-6 atrazine clodinafop-propargyl + cloquintocet-mexyl I-6 atrazine fenoxaprop-P-ethyl I-6 atrazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-6 atrazine flucarbazone-sodium I-6 atrazine propoxycarbazone-sodium I-6 atrazine alachlor I-6 atrazine dimethenamid I-6 atrazine S-dimethenamid I-6 atrazine metolachlor I-6 atrazine metolachlor + benoxacor I-6 atrazine S-metolachlor I-6 atrazine S-metolachlor + benoxacor I-6 atrazine acetochlor I-6 atrazine acetochlor + dichlormid I-6 atrazine acetochlor + R-29148 I-6 atrazine acetochlor + furilazole I-6 atrazine flufenacet I-6 metribuzin clodinafop-propargyl I-6 metribuzin clodinafop-propargyl + cloquintocet-mexyl I-6 metribuzin fenoxaprop-P-ethyl I-6 metribuzin fenoxaprop-P-ethyl + mefenpyr-diethyl I-6 metribuzin flucarbazone-sodium I-6 metribuzin propoxycarbazone-sodium I-6 metribuzin alachlor I-6 metribuzin dimethenamid I-6 metribuzin S-dimethenamid I-6 metribuzin metolachlor I-6 metribuzin metolachlor + benoxacor I-6 metribuzin metolachlor I-6 metribuzin metolachlor + benoxacor I-6 metribuzin acetochlor I-6 metribuzin acetochlor + dichlormid I-6 metribuzin acetochlor + R-29148 I-6 metribuzin acetochlor + furilazole I-6 metribuzin flufenacet I-6 terbuthylazine clodinafop-propargyl I-6 terbuthylazine clodinafop-propargyl + cloquintocet-mexyl I-6 terbuthylazine fenoxaprop-P-ethyl I-6 terbuthylazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-6 terbuthylazine flucarbazone-sodium I-6 terbuthylazine propoxycarbazone-sodium I-6 terbuthylazine alachlor I-6 terbuthylazine dimethenamid I-6 terbuthylazine S-dimethenamid I-6 terbuthylazine metolachlor I-6 terbuthylazine metolachlor + benoxacor I-6 terbuthylazine S-metolachlor I-6 terbuthylazine S-metolachlor + benoxacor I-6 terbuthylazine acetochlor I-6 terbuthylazine acetochlor + dichlormid I-6 terbuthylazine acetochlor + R-29148 I-6 terbuthylazine acetochlor + furilazole I-6 terbuthylazine flufenacet I-6 simazine clodinafop-propargyl I-6 simazine clodinafop-propargyl + cloquintocet-mexyl I-6 simazine fenoxaprop-P-ethyl I-6 simazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-6 simazine flucarbazone-sodium I-6 simazine propoxycarbazone-sodium I-6 simazine alachlor I-6 simazine dimethenamid I-6 simazine S-dimethenamid I-6 simazine metolachlor I-6 simazine metolachlor + benoxacor I-6 simazine S-metolachlor I-6 simazine S-metolachlor + benoxacor I-6 simazine acetochlor I-6 simazine acetochlor + dichlormid I-6 simazine acetochlor + R-29148 I-6 simazine acetochlor + furilazole I-6 simazine flufenacet I-6 cyanazine clodinafop-propargyl I-6 cyanazine clodinafop-propargyl + cloquintocet-mexyl I-6 cyanazine fenoxaprop-P-ethyl I-6 cyanazine fenoxaprop-P-ethyl + mefenpyr-diethyl I-6 cyanazine flucarbazone-sodium I-6 cyanazine propoxycarbazone-sodium I-6 cyanazine alachlor I-6 cyanazine dimethenamid I-6 cyanazine S-dimethenamid I-6 cyanazine metolachlor I-6 cyanazine metolachlor + benoxacor I-6 cyanazine S-metolachlor I-6 cyanazine S-metolachlor + benoxacor I-6 cyanazine acetochlor I-6 cyanazine acetochlor + dichlormid I-6 cyanazine acetochlor + R-29148 I-6 cyanazine acetochlor + furilazole I-6 cyanazine flufenacet

[0121] Further examples of combinations according to the invention comprising in each case one active compound of Group 1 and one or two active compounds of Group 2 and/or one active compound of Group 3 are listed in Table 2 below. TABLE 2 Active compound Compounds of of Group 1 Group 2 and/or 3 I-1 acetochlor I-1 acetochlor + dichlormid I-1 acetochlor + R-29148 I-1 acetochlor + furilazole I-1 alachlor I-1 amicarbazone I-1 amitrole I-1 atrazine I-1 bromacil I-1 carfentrazone-ethyl I-1 chlorimuron-ethyl I-1 cyanazine I-1 diclosulam I-1 dimethenamid I-1 S-dimethenamid I-1 diuron I-1 EPTC I-1 fentrazamide I-1 flucarbazone-sodium I-1 flufenacet I-1 flumetsulam I-1 glufosinate-ammonium I-1 glyphosate-isopropylammonium I-1 imazamox I-1 imazaquin I-1 imazamethapyr I-1 isoxaflutole I-1 mesotrione I-1 metolachlor I-1 metolachlor + benoxacor I-1 S-metolachlor I-1 S-metolachlor + benoxacor I-1 metosulam I-1 metribuzin I-1 nicosulfuron I-1 norflurazon I-1 pendimethalin I-1 propoxycarbazone-sodium I-1 rimsulfuron I-1 simazin I-1 sulcotrione I-1 sulfentrazone I-1 sulfometuron-methyl I-1 sulfosate I-1 terbuthylazine I-1 thifensulfuron-methyl I-1 trifluralin I-1 clodinafop-propargyl I-1 clodinafop-propargyl + cloquintocet-mexyl I-1 fenoxaprop-P-ethyl I-1 fenoxaprop-P-ethyl + mefenpyr-diethyl I-1 flufenacet + diflufenican I-1 flufenacet + isoxaflutole I-1 flufenacet + metosulam I-1 bromacil + diuron I-2 acetochlor I-2 acetochlor + dichlormid I-2 acetochlor + R-29148 I-2 acetochlor + furilazole I-2 alachlor I-2 amicarbazone I-2 amitrole I-2 atrazine I-2 bromacil I-2 carfentrazone-ethyl I-2 chlorimuron-ethyl I-2 cyanazine I-2 diclosulam I-2 dimethenamid I-2 S-dimethenamid I-2 diuron I-2 EPTC I-2 fentrazamide I-2 flucarbazone-sodium I-2 flufenacet I-2 flumetsulam I-2 glufosinate-ammonium I-2 glyphosate-isopropylammonium I-2 imazamox I-2 imazaquin I-2 imazamethapyr I-2 isoxaflutole I-2 mesotrione I-2 metolachlor I-2 metolachlor + benoxacor I-2 S-metolachlor I-2 S-metolachlor + benoxacor I-2 metosulam I-2 metribuzin I-2 nicosulfuron I-2 norflurazon I-2 pendimethalin I-2 propoxycarbazone-sodium I-2 rimsulfuron I-2 simazin I-2 sulcotrione I-2 sulfentrazone I-2 sulfometuron-methyl I-2 sulfosate I-2 terbuthylazine I-2 thifensulfuron-methyl I-2 trifluralin I-2 clodinafop-propargyl I-2 clodinafop-propargyl + cloquintocet-mexyl I-2 fenoxaprop-P-ethyl I-2 fenoxaprop-P-ethyl + mefenpyr-diethyl I-2 flufenacet + diflufenican I-2 flufenacet + isoxaflutole I-2 flufenacet + metosulam I-2 bromacil + diuron I-3 acetochlor I-3 acetochlor + dichlormid I-3 acetochlor + R-29148 I-3 acetochlor + furilazole I-3 alachlor I-3 amicarbazone I-3 amitrole I-3 atrazine I-3 bromacil I-3 carfentrazone-ethyl I-3 chlorimuron-ethyl I-3 cyanazine I-3 diclosulam I-3 dimethenamid I-3 S-dimethenamid I-3 diuron I-3 EPTC I-3 fentrazamide I-3 flucarbazone-sodium I-3 flufenacet I-3 flumetsulam I-3 glufosinate-ammonium I-3 glyphosate-isopropylammonium I-3 imazamox I-3 imazaquin I-3 imazamethapyr I-3 isoxaflutole I-3 mesotrione I-3 metolachlor I-3 metolachlor + benoxacor I-3 S-metolachlor I-3 S-metolachlor + benoxacor I-3 metosulam I-3 metribuzin I-3 nicosulfuron I-3 norflurazon I-3 pendimethalin I-3 propoxycarbazone-sodium I-3 rimsulfuron I-3 simazin I-3 sulcotrione I-3 sulfentrazone I-3 sulfometuron-methyl I-3 sulfosate I-3 terbuthylazine I-3 thifensulfuron-methyl I-3 trifluralin I-3 clodinafop-propargyl I-3 clodinafop-propargyl + cloquintocet-mexyl I-3 fenoxaprop-P-ethyl I-3 fenoxaprop-P-ethyl + mefenpyr-diethyl I-3 flufenacet + diflufenican I-3 flufenacet + isoxaflutole I-3 flufenacet + metosulam I-3 bromacil + diuron I-4 acetochlor I-4 acetochlor + dichlormid I-4 acetochlor + R-29148 I-4 acetochlor + furilazole I-4 alachlor I-4 amicarbazone I-4 amitrole I-4 atrazine I-4 bromacil I-4 carfentrazone-ethyl I-4 chlorimuron-ethyl I-4 cyanazine I-4 diclosulam I-4 dimethenamid I-4 S-dimethenamid I-4 diuron I-4 EPTC I-4 fentrazamide I-4 flucarbazone-sodium I-4 flufenacet I-4 flumetsulam I-4 glufosinate-ammonium I-4 glyphosate-isopropylammonium I-4 imazamox I-4 imazaquin I-4 imazamethapyr I-4 isoxaflutole I-4 mesotrione I-4 metolachlor I-4 metolachlor + benoxacor I-4 S-metolachlor I-4 S-metolachlor + benoxacor I-4 metosulam I-4 metribuzin I-4 nicosulfuron I-4 norflurazon I-4 pendimethalin I-4 propoxycarbazone-sodium I-4 rimsulfuron I-4 simazin I-4 sulcotrione I-4 sulfentrazone I-4 sulfometuron-methyl I-4 sulfosate I-4 terbuthylazine I-4 thifensulfuron-methyl I-4 trifluralin I-4 clodinafop-propargyl I-4 clodinafop-propargyl + cloquintocet-mexyl I-4 fenoxaprop-P-ethyl I-4 fenoxaprop-P-ethyl + mefenpyr-diethyl I-4 flufenacet + diflufenican I-4 flufenacet + isoxaflutole I-4 flufenacet + metosulam I-4 bromacil + diuron I-5 acetochlor I-5 acetochlor + dichlormid I-5 acetochlor + R-29148 I-5 acetochlor + furilazole I-5 alachlor I-5 amicarbazone I-5 amitrole I-5 atrazine I-5 bromacil I-5 carfentrazone-ethyl I-5 chlorimuron-ethyl I-5 cyanazine I-5 diclosulam I-5 dimethenamid I-5 S-dimethenamid I-5 diuron I-5 EPTC I-5 fentrazamide I-5 flucarbazone-sodium I-5 flufenacet I-5 flumetsulam I-5 glufosinate-ammonium I-5 glyphosate-isopropylammonium I-5 imazamox I-5 imazaquin I-5 imazamethapyr I-5 isoxaflutole I-5 mesotrione I-5 metolachlor I-5 metolachlor + benoxacor I-5 S-metolachlor I-5 S-metolachlor + benoxacor I-5 metosulam I-5 metribuzin I-5 nicosulfuron I-5 norflurazon I-5 pendimethalin I-5 propoxycarbazone-sodium I-5 rimsulfuron I-5 simazin I-5 sulcotrione I-5 sulfentrazone I-5 sulfometuron-methyl I-5 sulfosate I-5 terbuthylazine I-5 thifensulfuron-methyl I-5 trifluralin I-5 clodinafop-propargyl I-5 clodinafop-propargyl + cloquintocet-mexyl I-5 fenoxaprop-P-ethyl I-5 fenoxaprop-P-ethyl + mefenpyr-diethyl I-5 flufenacet + diflufenican I-5 flufenacet + isoxaflutole I-5 flufenacet + metosulam I-5 bromacil + diuron I-6 acetochlor I-6 acetochlor + dichlormid I-6 acetochlor + R-29148 I-6 acetochlor + furilazole I-6 alachlor I-6 amicarbazone I-6 amitrole I-6 atrazine I-6 bromacil I-6 carfentrazone-ethyl I-6 chlorimuron-ethyl I-6 cyanazine I-6 diclosulam I-6 dimethenamid I-6 S-dimethenamid I-6 diuron I-6 EPTC I-6 fentrazamide I-6 flucarbazone-sodium I-6 flufenacet I-6 flumetsulam I-6 glufosinate-ammonium I-6 glyphosate-isopropylammonium I-6 imazamox I-6 imazaquin I-6 imazamethapyr I-6 isoxaflutole I-6 mesotrione I-6 metolachlor I-6 metolachlor + benoxacor I-6 S-metolachlor I-6 S-metolachlor + benoxacor I-6 metosulam I-6 metribuzin I-6 nicosulfuron I-6 norflurazon I-6 pendimethalin I-6 propoxycarbazone-sodium I-6 rimsulfuron I-6 simazin I-6 sulcotrione I-6 sulfentrazone I-6 sulfometuron-methyl I-6 sulfosate I-6 terbuthylazine I-6 thifensulfuron-methyl I-6 trifluralin I-6 clodinafop-propargyl I-6 clodinafop-propargyl + cloquintocet I-6 fenoxaprop-P-ethyl I-6 fenoxaprop-P-ethyl + mefenpyr-diethyl I-6 flufenacet + diflufenican I-6 flufenacet + isoxaflutole I-6 flufenacet + metosulam I-6 bromacil + diuron

[0122] Surprisingly, it has now been found that the above-defined active compound combinations of the N-Aryl-uracils of the formula (I) and the abovementioned active compounds of Group 2 exhibit a particularly high herbicidal activity combined with very good crop plant compatibility and can be used for the selective control of monocotyledonous and dicotyledonous weeds in a variety of crops, in particular in cereals, such as, for example, wheat, barley or oats, and maize, and additionally also for controlling monocotyledonous and dicotyledonous weeds in the semi- and non-selective field. This effect is particularly pronounced in cereals. Likewise, the effect is particularly pronounced in maize.

[0123] Surprisingly, the herbicidal activity of the active compound combinations according to the invention of compounds of the abovementioned Groups 1 and 2 exceeds the total of the action of the individual active compounds considerably.

[0124] Thus, not just a complementation of actions but a synergistic effect is present which could not have been predicted. The new active compound combinations are well tolerated in a variety of crops, also effecting good control of weeds which are usually difficult to control. Thus, the novel active compound combinations are a valuable addition to the herbicides.

[0125] The synergistic effect of the active compound combinations according to the invention is particularly strongly pronounced in certain concentration ratios. However, the weight ratios of the active compounds in the active compound combinations may be varied within relatively wide ranges. In general, from 0.01 to 1000 parts by weight, preferably from 0.02 to 500 parts by weight and particularly preferably from 0.05 to 100 parts by weight of active compound of Group 2 are used per part by weight of active compound of the formula (I).

[0126] The following may be particularly emphasized as mixing components from amongst the active compounds of Group 3:

[0127] 1-methyl-hexyl 5-chloro-quinoxalin-8-oxy-acetate (cloquintocet-mexyl), ethyl 4,5-dihydro-5,5-diphenyl-3-isoxazolecarboxylate (isoxadifen-ethyl) and diethyl 1-(2,4-dichloro-phenyl)-4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylate (mefenpyr-diethyl), which are particularly suitable for improving the compatibility in cereals, and 4-dichloroacetyl-1-oxa-4-aza-spiro[4.5]-decane (AD-67), 1-dichloroacetyl-hexahydro-3,3,8a-trimethylpyrrolo[1,2-a]-pyrimidin-6(2H)-one (BAS-145138), 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine (benoxacor), 2,2-dichloro-N,N-di-2-propenyl-acetamide (dichlormid), 3-dichloroacetyl-5-(2-furanyl)-2,2-dimethyl-oxazolidine (furilazole, MON-13900) and 3-dichloroacetyl-2,2,5-trimethyl-oxazolidine (R-29148), which are particularly suitable for improving the compatibility in maize.

[0128] It must be considered as surprising that, from amongst a multiplicity of known safeners or antidotes capable of antagonizing the harmful effects of a herbicide on the crop plants, it is precisely the abovementioned compounds of Group 3 which are capable of almost completely compensating the harmful effect, on the crop plants, of active compounds of the formula (I) and their salts, if appropriate also in combination with one or more of the abovementioned active compounds of Group 2, without adversely affecting the herbicidal efficacy towards the weeds.

[0129] Surprisingly, it has also been found that the herbicidally active substance 2,4-dichlorophenoxy-acetic acid (2,4-D) and its derivatives, too, can play the safener role described above.

[0130] Accordingly, a preferred embodiment is also a mixture comprising a compound of the formula (I) and/or salts thereof on the one hand, and 2,4-D and/or its derivatives on the other hand, if appropriate in combination with one or more of the active compounds of Group 2 listed above. Typical derivatives of 2,4-D are, for example, its esters.

[0131] Surprisingly, it has also been found that the herbicidally active substances (4-chloro-2-methylphenoxy)acetic acid (MCPA) and (+−)-2-(4-chloro-2-methylphenoxy)propanoic acid (mecoprop) can also play a safener role. The compounds mentioned are described in the following patent applications: JP 63 072 605 und GB 00 820 180.

[0132] The compounds diethyl 1-(2,4-dichlorophenyl)-4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylate (mefenpyr-diethyl), 1-methyl-hexyl [(5-chloro-8-quinolinyl)oxy]acetate (cloquintocet-mexyl) and ethyl 1-(2,4-dichlorophenyl)-5-(trichloromethyl)-1H-1,2,4-triazole-3-carboxylate (fenchlorazole-ethyl) are described in the following patent applications: DE-A-39 39 503, EP-A-191 736 and DE-A-35 25 205. 2,4-D is a known herbicide.

[0133] The advantageous effect of the crop plant compatibility of the active compound combinations according to the invention is likewise particularly strongly pronounced at certain concentration ratios. However, the weight ratios of the active compounds in the active compound combinations can be varied within relatively wide ranges. In general, from 0.001 to 1000 parts by weight, preferably from 0.01 to 100 parts by weight and particularly preferably from 0.1 to 10 parts by weight of one of the crop plant compatibility-improving compounds mentioned above under (c) (antidotes/safeners) are used per part by weight of active compound of the formula (I).

[0134] All plants and plant parts can be treated in accordance with the invention. Plants are to be understood as meaning in the present context all plants and plant populations such as desired and undesired wild plants or crop plants (inclusive of naturally occurring crop plants). Crop plants can be plants which can be obtained by conventional plant breeding and optimization methods or by biotechnological and recombinant methods or by combinations of these methods, inclusive of the transgenic plants and inclusive of the plant varieties protectable or not protectable by plant breeders' rights. Plant parts are to be understood as meaning all aerial and subterranean plant parts and organs of the plants such as shoot, leaf, flower and root, examples which may be mentioned being leaves, needles, stalks, trunks, flowers, fruiting bodies, fruits, seeds, roots, tubers and rhizomes. The plant parts also include vegetative and generative propagation material, for example cuttings, tubers, rhizomes, seedlings and seeds.

[0135] The treatment according to the invention of the plant and plant parts with the active compounds is carried out directly or by allowing the compounds to act on the surroundings, environment or storage space by the customary treatment methods, for example by immersion, spraying, evaporation, fogging, scattering, painting on and, in the case of propagation material, in particular in the case of seeds, also by applying one or more coats.

[0136] Amongst the plants obtained by biotechnological and recombinant methods, or by combining these methods, plants which are emphasized are those which tolerate so-called ALS, 4-HPPD, EPSP and/or PPO inhibitors, such as, for example, Acuron plants.

[0137] The active compounds according to the invention can be used, for example, in the following plants:

[0138] Dicotyledonous weeds of the genera: Abutilon, Amaranthus, Ambrosia, Anoda, Anthemis, Aphanes, Atriplex, Bellis, Bidens, Capsella, Carduus, Cassia, Centaurea, Chenopodium, Cirsium, Convolvulus, Datura, Desmodium, Emex, Erysimum, Euphorbia, Galeopsis, Galinsoga, Galium, Hibiscus, Ipomoea, Kochia, Lamium, Lepidium, Lindernia, Matricaria, Mentha, Mercurialis, Mullugo, Myosotis, Papaver, Pharbitis, Plantago, Polygonum, Portulaca, Ranunculus, Raphanus, Rorippa, Rotala, Rumex, Salsola, Senecio, Sesbania, Sida, Sinapis, Solanum, Sonchus, Sphenoclea, Stellaria, Taraxacum, Thlaspi, Trifolium, Urtica, Veronica, Viola, Xanthium.

[0139] Dicotyledonous crops of the genera: Arachis, Beta, Brassica, Cucumis, Cucurbita, Helianthus, Daucus, Glycine, Gossypium, Ipomoea, Lactuca, Linum, Lycopersicon, Nicotiana, Phaseolus, Pisum, Solanum, Vicia.

[0140] Monocotyledonous weeds of the genera: Aegilops, Agropyron, Agrostis, Alopecurus, Apera, Avena, Brachiaria, Bromus, Cenchrus, Commelina, Cynodon, Cyperus, Dactyloctenium, Digitaria, Echinochloa, Eleocharis, Eleusine, Eragrostis, Eriochloa, Festuca, Fimbristylis, Heteranthera, Imperata, Ischaemum, Leptochloa, Lolium, Monochoria, Panicum, Paspalum, Phalaris, Phleum, Poa, Rottboellia, Sagittaria, Scirpus, Setaria, Sorghum.

[0141] Monocotyledonous crops of the genera: Allium, Ananas, Asparagus, Avena, Hordeum, Oryza, Panicum, Saccharum, Secale, Sorghum, Triticale, Triticum, Zea.

[0142] However, the use of the active compound combinations according to the invention is in no way restricted to these genera, but also extends in the same manner to other plants.

[0143] The active compound combinations to be used in accordance with the invention can be employed not only in conventional cultivation methods (suitably spaced row crops), in plantation crops (for example grapevines, fruit, citrus) and in industrial plants and railtracks, on paths and squares, but also for stubble treatment and in the minimum tillage method. They are furthermore suitable as dessicants (haulm killing in, for example, potatoes) or as defoliants (for example in cotton). They are furthermore suitable for use on non-crop areas. Other fields of application are nurseries, forests, grassland and the production of ornamentals.

[0144] The active compound combinations can be converted into the customary formulations such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspo-emulsion concentrates, natural and synthetic materials impregnated with active compound, and microencapsulations in polymeric materials.

[0145] These formulations are produced in a known manner, for example by mixing the active compounds with extenders, that is, liquid solvents and/or solid carriers, optionally with the use of surfactants, that is, emulsifiers and/or dispersants and/or foam formers.

[0146] In the case of the use of water as an extender, organic solvents can, for example, also be used as cosolvents. The following are essentially suitable as liquid solvents: aromatics such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons such as cyclohexane or paraffins, for example mineral oil fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulphoxide, or else water.

[0147] Solid carriers which are suitable are:

[0148] for example ammonium salts and ground natural minerals such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic materials such as highly-dispersed silica, alumina and silicates; suitable solid carriers for granules are: for example crushed and fractionated natural rocks such as calcite, marble, pumice, sepiolite and dolomite, or else synthetic granules of inorganic and organic meals, and granules of organic material such as sawdust, coconut shells, maize cobs and tobacco stalks; suitable emulsifiers and/or foam formers are: for example nonionic and anionic emulsifiers such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkylsulphonates, alkyl sulphates, arylsulphonates, or else protein hydrolysates; suitable dispersants are: for example lignin sulphite waste liquors and methylcellulose.

[0149] Tackifiers such as carboxymethylcellulose and natural and synthetic polymers in the form of powders, granules or latices, such as gum arabic, polyvinyl alcohol and polyvinyl acetate, or else natural phospholipids such as cephalins and lecithins and synthetic phospholipids can be used in the formulations. Other additives can be mineral and vegetable oils.

[0150] It is possible to use colorants such as inorganic pigments, for example iron oxide, titanium oxide and Prussian Blue, and organic dyestuffs, such as alizarin dyestuffs, azo dyestuffs and metal phthalocyanine dyestuffs, and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.

[0151] The formulations generally comprise between 0.1 and 95 percent by weight of active compounds, preferably between 0.5 and 90%.

[0152] The active compound combinations according to the invention are generally applied in the form of ready mixes. However, the active compounds contained in the active compound combinations may also be applied in the form of individual formulations which are mixed upon use, that is, in the form of tank mixes.

[0153] The new active compound combinations, as such or in their formulations, may furthermore also be used as a mixture with other known herbicides, again with ready mixes or tank mixes being possible. A mixture with other known active compounds such as fungicides, insecticides, acaricides, nematicides, bird repellants, growth substances, plant nutrients and soil conditioners is also possible. It may furthermore be advantageous for specific applications, in particular for the post-emergence method, to incorporate into the formulations plant-tolerated mineral or vegetable oils (for example the commercial product “Rako Binol”) or ammonium salts such as, for example, ammonium sulphate or ammonium thiocyanate, as further additives.

[0154] The new active compound combinations can be used as such, in the form of their formulations or the use forms which can be prepared from these formulations by further dilution, such as ready-to-use solutions, suspensions, emulsions, powders, pastes and granules. Application is effected in the customary manner, for example by pouring, spraying, atomizing, dusting or broadcasting.

[0155] The active compound combinations according to the invention can be applied before and after emergence of the plants, that is to say by the pre- and post-emergence method. They may also be incorporated into the soil prior to sowing.

[0156] The good herbicidal action of the new active compound combinations can be seen from the examples which follow. While the individual active compounds show weaknesses with regard to their herbicidal action, the combinations all show a very good herbicidal action which exceeds a simple sum of actions.

[0157] A synergistic effect in herbicides is always present when the herbicidal action of the active compound combination exceeds the action of the active compounds when applied individually.

[0158] The expected action for a given combination of two herbicides can be calculated as follows (cf. COLBY, S. R.: “Calculating synergistic and antagonistic responses of herbicide combinations”, Weeds 15, Pages 20-22, 1967):

[0159] If

[0160] X=% damage by herbicide A (active compound of the formula I) at an application rate of p kg/ha

[0161] and

[0162] Y=% damage by herbicide B (active compound of the formula II) at an application rate of q kg/ha

[0163] and

[0164] E=the expected damage of herbicides A+B at an application rate of p+q kg/ha,

[0165] then

[0166] E=X+Y−(X*Y/100).

[0167] If the actual damage exceeds the calculated value, the combination has a superadditive effect, that is to say a synergistic effect.

[0168] The theoretically expected activity for a given combination of three herbicides can likewise be found in the literature mentioned above.

USE EXAMPLES Example A

[0169] Pre-Emergence-Test

[0170] Solvent: 2 to 3 parts by weight of acetone or N,N-dimethyl-formamide

[0171] Emulsifier: 1 part by weight of alkylaryl polyglycol ether

[0172] To produce a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amount of solvent, the stated amount of emulsifier is added and the concentrate is diluted with water to the desired concentration. Formulated products are dissolved in water and then diluted with water to the desired concentration.

[0173] The solutions of the other mixing components (active compounds or safeners) are prepared analogously. The separately prepared solutions of the various mixing components are then combined and, if appropriate, additional substances (formulation auxiliaries, additives, etc.) are added and, if appropriate, water is added to prepare the desired dilution.

[0174] Seeds of the test plants are sown in standard soil. After 24 hours, the soil is sprayed with the preparation of active compound such that the particular amount of active compound desired in each case is applied per unit area. The concentration of active compound in the spray liquor is chosen such that the particular amount of active compound desired in each case is applied in 500 litres of water per hectare. The containers with the test plants are kept in a greenhouse at controlled temperature and controlled illumination until evaluation.

[0175] After three weeks, the degree of damage to the plants is rated in % damage in comparison to the development of the untreated control. The figures denote

[0176] 0% no effect/no damage (like untreated control)

[0177] 100%=total destruction

[0178] In this test, for example, combinations of the compound (I-3) with the compounds 4-dichloroacetyl-1-oxa-4-aza-spiro[4.5]-decane (AD-67) and phenylmethyl 2-chloro-4-trifluoromethyl-thiazole-5-carboxylate (flurazole) show considerably better compatibility with crop plants, such as, for example, maize, than the compound (I-3) on its own (cf. Table A1). TABLE A1 Pre-emergence test in maize Application Number rate Active Application of Average Active (g of compound rate (g of maize damage compound 1 a.i./ha) 2 a.i./ha) plants (%) I-3 90 48 36 I-3 60 44 17 I-3 90 AD-67 500 45 21 I-3 60 AD-67 500 47 10 I-3 90 AD-67 60 42 20 I-3 60 AD-67 60 39 18 I-3 90 AD-67 30 47 21 I-3 60 AD-67 30 47 14 I-3 90 flurazole 500 48 18 I-3 60 flurazole 500 47 8 I-3 90 flurazole 60 48 27 I-3 60 flurazole 60 46 10 I-3 90 flurazole 30 33 36 I-3 60 flurazole 30 43 16

[0179] Furthermore, in this test combinations of the compound (I-6) with the compound diethyl 1-(2,4-dichlorophenyl)-4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylate (mefenpyr-diethyl) show considerably better compatibility with crop plants, such as, for example, barley and wheat, than the compound (I-6) on its own (cf. Table A2). TABLE A2 Post-emergence test in barley and wheat Application rates Winter Summer Durum Winter Summer Summer Durum Active (g of barley wheat (21 wheat wheat wheat (5 wheat (22 wheat compounds a.i./ha) (21 days) days) (5 days) (21 days) days) days) (22 days) (I-6) 30 30 30 30 — 60 30 20 (I-6) 15 20 20 20 10 50 20 — (I-6) + 30 + 30 20 20 20 — 50 20 10 mefenpyrdiethyl (I-6) + 15 + 15 10 10 10  5 40 10 — mefenpyrdiethyl

[0180] Furthermore, in this test combinations of the compound (I-6) with the compounds 1-methylhexyl 5-chloro-quinoxalin-8-oxy-acetate (cloquintocet-mexyl) and ethyl 1-(2,4-dichloro-phenyl)-5-trichloromethyl-1H-1,2,4-triazole-3-carboxylate (fenchlorazol-ethyl) show considerably better compatibility with crop plants, such as, for example, barley and wheat, than the compound (I-6) on its own (cf. Table A3). TABLE A3 Post-emergence test in barley and wheat Application rates Winter Winter Winter Winter Winter Winter (g of wheat wheat barley barley barley wheat Active compounds a.i./ha) (5 days) (20 days) (5 days) (21 days) (22 days) (22 days) (I-6) 15 30 20 60 50 — — (I-6)  8 30 10 40 50 20 20 (I-6)  4 20 10 30 50 10 20 (I-6) + cloquintocetmexyl 15 + 15 30 10 40 40 — — (I-6) + cloquintocetmexyl 4 + 4 10  5 20 20  5  5 (I-6) + cloquintocetmexyl  8 + 25 — — — —  5  5 (I-6) + fenchlorazol- 15 + 15 20 10 30 30 — — ethyl (I-6) + fenchlorazol- 8 + 8 20 10 30 20 10 — ethyl (I-6) + fenchlorazol- 4 + 4 10  5 20 20 — — ethyl (I-6) + fenchlorazol-  8 + 25 10 — ethyl

[0181] Furthermore, in this test combinations of the compound (I-6) with the compound 2,2-dichloro-N,N-di-2-propenyl-acetamide (dichlormid) show considerably better compatibility with crop plants, such as, for example, barley and wheat, than the compound (I-6) on its own (cf. Table A4). TABLE A4 Post-emergence test in barley and wheat Summer Summer Winter Application rates wheat wheat barley Active compounds (g of a.i./ha) (5 days) (21 days) (5 days) (I-6) 30 50 40 — (I-6) 15 40 30 50 (I-6) + dichlormid 30 + 30 30 20 — (I-6) + dichlormid 15 + 15 20 20 30

[0182] Furthermore, in this test combinations of the compound (I-6) with the compound 4,6-dichloro-2-phenyl-pyrimidine (fenclorim) show considerably better compatibility with crop plants, such as, for example, barley and wheat, than the compound (I-6) on its own (cf. Table A5). TABLE A5 Post-emergence test in barley and wheat Application rates Winter Winter Summer Summer Durum Durum Active (g of barley barley wheat wheat wheat wheat compounds a.i./ha) (5 days) (21 days) (5 days) (21 days) (5 days) (21 days) (I-6) 30 50 20 50 40 30 20 (I-6) 15 50 20 40 30 20 20 (I-6) + fenclorim 30 + 30 30 10 40 20 10  5 (I-6) + fenclorim 15 + 15 30 10 20 10 10  5

[0183] Furthermore, in this test, combinations of the compound (I-6) with the compound 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine (benoxacor) show considerably better compatibility with crop plants, such as, for example, barley and wheat, than the compound (I-6) on its own (cf. Table A6). TABLE A6 Post-emergence test in barley and wheat Application Summer Summer Durum Winter Active rates wheat wheat wheat barley compounds (g of a.i./ha) (5 days) (21 days) (21 days) (5 days) (I-6) 30 50 40 20 — (I-6) 15 40 30 20 50 (I-6) + 30 + 30 40 20 10 — benoxacor (I-6) + 15 + 15 30 20 10 30 benoxacor

[0184] Furthermore, in this test combinations of the compound (I-3) with the compounds 2,4-D and glyphosate-isopropylammonium show considerable synergistic activity (cf. Table A7). TABLE A7 Post-emergence test (in brackets: values calculated according to Colby) Application rates g of Active compounds a.i./ha) Amaranthus Galium (I-3)  8 — 40 (I-3)  4 70 — 2,4-D  86 30  0 (I-3) + 2,4-D 4 + 86 90 (79) — (I-3) + 2,4-D 8 + 86 — 99 (40) glyphosate-iso- 125 —  0 propylammonium (I-3) + glyphosate-iso- 8 + 125 — 80 (40) propylammonium

[0185] Furthermore, in this test, combinations of the compound (I-3) with the compound sulfentrazone show considerable synergistic activity (Table A8). TABLE A8 Post-emergence test (in brackets: values calculated according to Colby) Appli- cation Active rates (g of compounds a.i./ha) Datura Abutilon Amaranthus Chenopodium Galium Matricaria Polygonum Solanum Veronica (I-3)  8  60 — — —  0 —  60 —  70 (I-3)  4  30  0  0  0 —  70 —  30  0 sulfentrazone 125  0 — — — —  0  50  0  20 sulfentrazone  60  0  0  90  60  0 — —  0  0 (I-3) +  8 + 125 100 — — — — — 100 — 100 sulfentrazone (60) (80) (76) (I-3) +  4 + 125 100 — — — — 100 — 100 100 sulfentrazone (30) (70) (30) (20) (I-3) +  8 + 60 100 — — — 100 — — — 100 sulfentrazone (60) (0) (70) (I-3) +  4 + 60  70 98 100 100 — — —  95 100 sulfentrazone (30) (0) (90) (60) (30) (0) 

[0186] Furthermore, in this test combinations of the compound (I-3) with the compound imazamox show considerable synergistic activity (cf. Table A9). TABLE A9 Post-emergence test (in brackets: values calculated according to Colby) Application rates (g of Active compounds a.i./ha) Veronica Solanum (I-3)  8  70 — (I-3)  4  0 30 imazamox 15  0 imazamox  8  0 — (I-3) + imazamox 8 + 8 100 (70) — (I-3) + imazamox 4 + 8  80 (0) — (I-3) + imazamox 4 + 15 — 95 (30)

[0187] Furthermore, in this test, combinations of the compound (I-3) with the compound acetochlor show considerable synergistic activity (cf. Table A10). TABLE A10 Pre-emergence test (in brackets: values calculated according to Colby) Application rates Active (g of compounds a.i./ha) Alopecurus Cyperus Digitaria Echinochloa Setaria Abutilon Matricaria Polygonum Stellaria (I-3)  8  0 —  20 — —  50 —  90 — (I-3)  4 —  0  0  0  0  20  50  0  80 acetochlor 250 — 60 — 80 80  40 —  30 — acetochlor 125 30 60  80 — —  0  90  30  80 (I-3) +  8 + 125 80 — 100 — — 100 — — — acetochlor (30) (84) (50) (I-3) +  4 + 125 — 90 90 — — 100 100 (95)  80 (30) 100 acetochlor (60) (80) (20) (96) (I-3) +  8 + 250 — — — — — 100 — 100 (93) — acetochlor (70) (I-3) +  4 + 250 — 99 — 95 99 — — 100 (30) — acetochlor (60) (80) (80)

[0188] Furthermore, in this test combinations of the compound (I-3) with the compound metolachlor show considerable synergistic activity (cf. Table A11). TABLE A11 Pre-emergence test (in brackets: values calculated according to Colby) Application Active rates (g of compounds a.i./ha) Digitaria Abutilon Stellaria Ipomoea Viola (I-3)  8  20  50 — —  90 (I-3)  4  20  80  30 — metolachlor 250  90  30  80  30 — metolachlor 125  30  30 —  50 (I-3) + metolachlor  8 + 250 100 100 — — — (92) (65) (I-3) + metolachlor  8 + 125 — 100 — 100 100 (65) (51) (95) (I-3) + metolachlor  4 + 125 — 100 100 — — (44) (86)

[0189] Furthermore, in this test combinations of the compound (I-3) with the compound isoxaflutole show considerable synergistic activity (cf. Table A12). TABLE A12 Pre-emergence test (in brackets: values calculated according to Colby) Application Active rates (g of compounds a.i./ha) Alopecurus Digitaria Polygonum Abutilon Datura (I-3)  8  0 20  90  40  30 (I-3)  4 —  0 —  20 — Isoxaflutole 60 40 — — —  90 Isoxaflutole 30 — 90  0  80 — (I-3) + Isoxaflutole 8 + 60 80 — — — 100 (40) (93) (I-3) + Isoxaflutole 8 + 30 — 99 100 100 — (92) (90) (88) (I-3) + Isoxaflutole 4 + 30 — 99 — 100 — (90) (84)

[0190] Furthermore, in this test combinations of the compound (I-3) with the compound flufenacet show considerable synergistic activity (cf. Table A13). TABLE A13 Pre-emergence test (in brackets: values calculated according to Colby) Application Active rates (g of compounds a.i./ha) Digitaria Setaria Abutilon Datura Ipomoea Matricaria Stellaria (I-3)  8  20  0  50 80 —  90 — (I-3)  4 —  0  20 — 50  50  80 flufenacet 125 — —  20 — 30  60  70 flufenacet  60  80  80  20 40 — —  50 (I-3) + flufenacet 8 + 125 — — 100 — — 100 — (60) (96) (I-3) + flufenacet 8 + 60  100 100 (80) 100 99 — — — (84) (60) (88) (I-3) + flufenacet 4 + 125 — — 100 — 99 100 100 (36) (65) (80) (94) (I-3) + flufenacet 4 + 60  — 100 (80)  95 — — — 100 (36) (90)

[0191] Furthermore, in this test combinations of the compound (I-3) with the compound metribuzin show considerable synergistic activity (cf. Table A14). TABLE A14 Pre-emergence test (in brackets: values calculated according to Colby) Application Active rates (g of compounds a.i./ha) Abutilon Datura Echinochloa Chenopodium (I-3)  8  50 80 — — (I-3)  4  20 —  0  80 metribuzin 125 — — 80 — metribuzin  60  90 30 —  50 (I-3) + metribuzin 4 + 125 — — 95 — (80) (I-3) + metribuzin 8 + 60  100 100 (86) — — (95) (I-3) + metribuzin 4 + 60  100 — — 100 (92) (96)

[0192] Furthermore, in this test combinations of the compound (I-3) with the compound amicarbazone show considerable synergistic activity (cf. Table A15). TABLE A15 Pre-emergence test (in brackets: values calculated according to Colby) Application Active rates (g of compounds a.i./ha) Alopecurus Digitaria Echinochloa Eriochloa Setaria Datura (I-3)  8  0  20  0 50  0 80 (I-3)  4  0 — — 30  0 — amicarbazone 60 20  60 0 70  20 20 (I-3) + amicarbazone 8 + 60 80 100 90 95 100 99 (20) (68) (0) (85) (20) (84) (I-3) + amicarbazone 4 + 60 80 — — 95 100 — (20) (79) (20)

[0193] Furthermore, in this test combinations of the compound (I-3) with the compound sulcotrione show considerable synergistic activity (cf. Table A16). TABLE A16 Pre-emergence test (in brackets: values calculated according to Colby) Application rates Active (g of compounds a.i./ha) Abutilon Stellaria Matricaria Cyperus Datura Ipomoea (I-3)  8  50 —  90  30  30  30 (I-3)  4  20  80  50 — — — sulcotrione 60  80  80 — — —  80 sulcotrione 30  70 —  40  90  50 — (I-3) + sulcotrione 8 + 60 100 — — — — 100 (90) (86) (I-3) + sulcotrione 4 + 60 100 100 — — — — (84) (96) (I-3) + sulcotrione 8 + 30 100 — 100 100 100 — (85) (94) (93) (65) (I-3) + sulcotrione 4 + 30 100 —  99 — — (76) (70)

[0194] Furthermore, in this test combinations of the compound (I-3) with the compounds flufenacet and amicarbazone show considerable synergistic activity (cf. Table A17). TABLE A17 Pre-emergence test (in brackets: values calculated according to Colby) Application rates Active (g of compounds a.i./ha) Digitaria Eriochloa Abutilon Cassia Datura Ipomoea Setaria Chenopodium (I-3)  8 20 —  50 —  80 —  0 — (I-3)  4  0 30  20  40  30 50  0  80 flufenacet 60 80 —  20  60  40 30  90  50 flufenacet 30 80 80  20 —  20 30  70  30 amicarbazone 60 60 —  99 —  20 —  30 — amicarbazone 30 20 30  20  70  0 50  20  50 (I-3) + flufenacet + 8 + 60 + 30 99 — 100 — 100 — 100 — amicarbazone (87) (68) (88) (92) (I-3) + flufenacet + 8 + 30 + 30 99 — 100 — 100 — 100 — amicarbazone (87) (68) (84) (76) (I-3) + flufenacet + 4 + 30 + 30 — 100 100 — — 99 100 100 amicarbazone (90) (49) (83) (76) (93) (I-3) + flufenacet + 4 + 60 + 30 — — 100 100 100 99 100 100 amicarbazone (49) (93) (58) (83) (92) (95)

[0195] Furthermore, in this test combinations of the compound (I-3) with the compounds flufenacet and metribuzin show considerable synergistic activity (cf. Table A18). TABLE A18 Pre-emergence test (in brackets: values calculated according to Colby) Application rates Active (g of compounds a.i./ha) Alopecurus Bromus Digitaria Echinochloa Abutilon Datura Galium Ipomoea Polygonum (I-3)  8 — —  20  0  50  80  30 — — (I-3)  4  0  0  0 —  20 — —  50  0 flufenacet 60 70 30  80  90  20  40 —  30  30 flufenacet 30 — —  80 —  20  20  30 — — metribuzin 60 — —  80  0  90  30  0 — 40 metribuzin 30  0  0  30 —  80  20 —  0 — (I-3) + 8 + 60 + 60 — — — 100 100 100 — — — flufenacet + (90) (96) (92) metribuzin (I-3) + 8 + 30 + 60 — — — — 100 100 100 — — flufenacet + (96) (89) (51) metribuzin (I-3) + 4 + 60 + 60 — — 100 — 100 — — — 90 flufenacet + (96) (94) (58) metribuzin (I-3) + 4 + 60 + 30 90 80 100 — 100 — — 100 — flufenacet + (70) (30) (86) (87) (65) metribuzin (I-3) + 4 + 30 + 60 — — 100 — 100 — — — — flufenacet + (96) (94) metribuzin (I-3) + 8 + 30 + 30 — — — — 100 100 — — — flufenacet + (92) (87) metribuzin

[0196] Furthermore, in this test combinations of the compound (I-3) with the compounds flufenacet and amicarbazone show considerable synergistic activity (cf. Table A19). TABLE A19 Pre-emergence test (in brackets: values calculated according to Colby) Application rates Active compounds (g of a.i./ha) Lolium Polygonum (I-3)  8  20 — (I-3)  4 —  0 flufenacet 60  80 — flufenacet 30 — 20 amicarbazone 60 — 80 amicarbazone 30  0 — (I-3) + flufenacet + amicarbazone 8 + 60 + 30 100 — (84) (I-3) + flufenacet + amicarbazone 4 + 30 + 60 — 99 (84)

[0197] Furthermore, in this test combinations of the compound (I-3) with the compound acetochlor show considerable synergistic activity (cf. Table A20). TABLE A20 Pre-emergence test (in brackets: values calculated according to Colby) Application rates Active (g of compounds a.i./ha) Lolium Chenopodium Datura Galium Ipomoea (I-3)  8 — —  30 20  30 (I-3)  4  0 80  0 —  30 acetochlor 250  90 —  50 20  20 acetochlor 125 — 30  30  0  0 (I-3) + acetochlor 8 + 250 — — 100 95 100 (65) (36) (44) (I-3) + acetochlor 8 + 125 — —  99 80 100 (51) (20) (30) (I-3) + acetochlor 4 + 250 100 — 100 —  95 (90) (50) (44) (I-3) + acetochlor 4 + 125 — 90  95 —  95 (86) (30) (30)

[0198] Furthermore, in this test combinations of the compound (I-3) with the compound flufenacet show considerable synergistic activity (cf. Table A21). TABLE A21 Pre-emergence test (in brackets: values calculated according to Colby) Application rates Active (g of compounds a.i./ha) Chenopodium Datura Ipomoea Polygonum (I-3)  8 — —  30  90 (I-3)  4  80  0 —  40 Flufenacet 125 — 50  80  30 flufenacet  60  50 —  70  0 (I-3) + flufenacet 8 + 125 — — 100 100 (86) (93) (I-3) + flufenacet 4 + 125 — 99 — 100 (50) (58) (I-3) + flufenacet 8 + 60  — —  95 100 (79) (90) (I-3) + flufenacet 4 + 60  100 — — — (90)

[0199] Furthermore, in this test combinations of the compound (I-3) with the compound amicarbazone show considerable synergistic activity (cf. Table A22). TABLE A22 Pre-emergence test (in brackets: values calculated according to Colby) Application Active rates (g of compounds a.i./ha) Cassia Datura Polygonum (I-3)  8  50 — — (I-3)  4 —  0 40 amicarbazone 125 — 50 90 amicarbazone  60  80 — — (I-3) + amicarbazone 8 + 60 100 — — (90) (I-3) + amicarbazone 4 + 125 — 90 (50) 99 (94)

[0200] Furthermore, in this test combinations of the compound (I-3) with the compounds flufenacet and metribuzin show considerable synergistic activity (cf. Table A23). TABLE A23 Pre-emergence test (in brackets: values calculated according to Colby) Application Active rates (g of compounds a.i./ha) Eriochloa Lolium Setaria Chenopodium Galium Ipomoea (I-3)  8  50 —  0 — — 30 (I-3)  4 —  0  0  80  0 — flufenacet 60  90 —  90  50 40 — flufenacet 30 — 70  70  30 — 50 metribuzin 60  0 —  80 — 20  0 metribuzin 30 —  0  20  30 — — (I-3) + flufenacet + metribuzin 8 + 60 + 60 100 — — — — — (95) (I-3) + flufenacet + metribuzin 8 + 30 + 60 — — 100 — — 90 (94) (65) (I-3) + flufenacet + metribuzin 4 + 60 + 60 — — — — 95 — (52) (I-3) + flufenacet + metribuzin 4 + 60 + 30 — — — 100 — — (93) (I-3) + flufenacet + metribuzin 4 + 30 + 60 — 95 — — — — (70) (I-3) + flufenacet + metribuzin 8 + 30 + 30 — — 100 — — — (76)

[0201] Furthermore, in this test combinations of the compound (I-3) with the compound trifluralin show considerable synergistic activity (cf. Table A24). TABLE A24 Pre-emergence test (in brackets: values calculated according to Colby) Application rates Active (g of compounds a.i./ha) Echinochloa Setaria Lolium Cassia Veronica (I-3)  8  30  30 — — — (I-3)  4  30 —  0  0  30 trifluralin 500  95 — — —  95 trifluralin 250 —  95  95  80 — (I-3) + trifluralin 8 + 500  99 — — — — (96) (I-3) + trifluralin 4 + 500 100 — — — 100 (96) (96) (I-3) + trifluralin 8 + 250 — 100 — — — (96) (I-3) + trifluralin 4 + 250 — — 100 100 — (95) (80)

[0202] Furthermore, in this test combinations of the compound (I-3) with the compound atrazine show considerable synergistic activity (cf. Table A25). TABLE A25 Pre-emergence test (in brackets: values calculated according to Colby) Application rates Active (g of compounds a.i./ha) Avena Bromus Cyperus Lolium (I-3)  8  40 —  50  60 (I-3)  4 —  0 — — atrazine 500  80  70  50  90 (I-3) + atrazine 8 + 500 100 100 100 (88) (75) (96) (I-3) + atrazine 4 + 500 — 100 — — (70)

[0203] Furthermore, in this test combinations of the compound (I-3) with the compounds isoxaflutole and metribuzin show considerable synergistic activity (cf. Table A26). TABLE A26 Pre-emergence test (in brackets: values calculated according to Colby) Application rates Active (g of compounds a.i./ha) Avena Digitaria Echinochloa Lolium Setaria Cassia Matricaria (I-3)  8 — —  30  30  30  30 70 (I-3)  4 40  30  0  30  0 — 30 isoxaflutole  60 — —  40  50  30 — 40 isoxaflutole  30 30  80  30  30  30  70 20 metribuzin 125 40  90  80  70  80 — 70 metribuzin  60 — —  30 — —  80 60 (I-3) + isoxaflutole + metribuzin 8 + 60 + 125 — — — 100 100 — 99 (89) (90) (95) (I-3) + isoxaflutole + metribuzin 4 + 60 + 125 — — 100 — — — 99 (88) (87) (I-3) + isoxaflutole + metribuzin 8 + 30 + 60  — — — — — 100 99 (96) (90) (I-3) + isoxaflutole + metribuzin 4 + 30 + 125 99 100 100 100 100 — 95 (75) (98) (86) (85) (86) (83) (I-3) + isoxaflutole + metribuzin 8 + 60 + 60  — — 100 — — — 99 (71) (93)

[0204] Furthermore, in this test combinations of the compound (I-3) with the compound foramsulfuron show considerable synergistic activity (cf. Table A27). TABLE A27 Pre-emergence test (in brackets: values calculated according to Colby) Application Active rates (g of compounds a.i./ha) Abutilon Cassia Polygonum (I-3)  8  95 30 20 foramsulfuron 30  50 — 40 foramsulfuron 15 — 50 — (I-3) + foramsulfuron 8 + 30 100 (97) — 99 (52) (I-3) + foramsulfuron 8 + 15 — 99 (65) —

[0205] In this test, it is furthermore possible to demonstrate that in particular compounds of Group 3 are capable of antagonizing the damaging effect of active compounds of the formula (I) in crop plants. (Tab. A28-A32). TABLE A28 Pre-emergence test in maize Application rates Maize Maize Maize Active compounds (g of a.i./ha) (7 days) (12 days) (21 days) (I-3) 90 20 — 36 (I-3) 60 10 20 17 (I-3) + flurazole 90 + 500 10 — 18 (I-3) + flurazole 60 + 500  5  5  8 (I-3) + flurazole 90 + 60 — — 27

[0206] TABLE A29 Pre-emergence test in maize Application rates Maize Active compounds (g of a.i./ha) Maize (12 days) (21 days) (I-3) 90 30 36 (I-3) 60 20 — (I-3) + AD-67 90 + 500 15 21 (I-3) + AD-67 60 + 500  5 — (I-3) + AD-67 90 + 60 20 20 (I-3) + AD-67 60 + 60  5 — (I-3) + AD-67 90 + 30 — 21

[0207] TABLE A30 Pre-emergence test in maize Application rates Maize Maize Maize Active compounds (g of a.i./ha) (7 days) (12 days) (21 days) (I-6) 90 60 60 30 (I-6) 60 30 — — (I-6) + AD-67 90 + 500 30 40 19 (I-6) + AD-67 90 + 60 20 20 24 (I-6) + AD-67 90 + 30 20 30 — (I-6) + AD-67 60 + 30 10 — —

[0208] TABLE A31 Pre-emergence test in maize Application rates Maize Maize Maize Active compounds (g of a.i./ha) (7 days) (12 days) (21 days) (I-3) 90 20 30 29 (I-3) + AD-67 90 + 500    5  8 (I-3) + AD-67 90 + 60  5  5 11 (I-3) + AD-67 90 + 30 — 10 16

[0209] TABLE A32 Pre-emergence test in maize Application rates Maize Maize Maize Active compounds (g of a.i./ha) (7 days) (12 days) (21 days) (I-5) 90 60 70 64 (I-5) 60 20 30 18 (I-5) + AD-67 90 + 500 10 5 20 (I-5) + AD-67 60 + 500 — 10 6 (I-5) + AD-67 90 + 60 30 30 16 (I-5) + AD-67 60 + 60  5 10 9 (I-5) + AD-67 60 + 30 — 10 8 

1. Herbicidal compositions, characterized in that they comprise an effective amount of active compound combination comprising (a) at least one N-aryl-uracil of the formula (I)

in which R¹ represents hydrogen, amino or optionally cyano-, halogen- or C₁-C₄-alkoxy-substituted alkyl having 1 to 5 carbon atoms, R² represents optionally halogen-substituted alkyl having 1 to 5 carbon atoms, R³ represents hydrogen, halogen or optionally halogen-substituted alkyl having 1 to 5 carbon atoms, R⁴ represents hydrogen, cyano or halogen, R⁵ represents cyano, thiocarbamoyl or halogen, and R⁶ represents nitro, cyano, carboxyl, carbamoyl, thiocarbamoyl, hydroxyl, mercapto, amino, hydroxyamino, aminosulphonyl, halogen, represents in each case optionally cyano-, hydroxyl-, C₁-C₄-alkoxy-, C₁-C₄-alkyl-carbonyl-, C₁-C₄-alkoxy-carbonyl-, C₂-C₄-alkenyloxy-carbonyl-, C₂-C₄-alkinyloxy-carbonyl-, C₁-C₄-alkylamino-carbonyl-, di-(C₁-C₄-alkyl)-amino-carbonyl-, phenoxycarbonyl- and/or phenylaminocarbonyl-substituted alkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl, alkylcarbonyl, alkoxycarbonyl or alkylamino having in each case up to 6 carbon atoms, represents in each case optionally cyano-, carboxyl-, halogen- and/or C₁-C₄-alkoxy-carbonyl-substituted alkenyl, alkinyl, alkenyloxy or alkinyloxy having in each case up to 6 carbon atoms, represents in each case optionally halogen- or C₁-C₄-alkoxy-substituted alkylcarbonylamino, alkoxycarbonylamino, alkylsulphonylamino, N,N-bis-alkylsulphonyl-amino or N-alkylcarbonyl-N-alkylsulphonyl-amino having in each case up to 6 carbon atoms in the alkyl groups, or represents phenyloxy, naphthyloxy, N-phenylcarbonyl-N-alkylsulphonyl-amino, N-pyridylcarbonyl-N-alkylsulphonyl-amino, N-furylcarbonyl-N-alkylsulphonyl-amino or N-thienylcarbonyl-N-alkylsulphonyl-amino having in each case up to 6 carbon atoms in the alkyl groups and being in each case optionally substituted by cyano or halogen, or by C₁-C₄-alkyl, C₁-C₄-alkoxy or C₁-C₄-alkoxycarbonyl (which are in each case optionally substituted by C₁-C₄-alkoxy-carbonyl, C₃-C₄-alkenyloxy-carbonyl or C₃-C₄-alkinyloxy-carbonyl), (“active compounds of Group 1”) and (b) at least one compound from a second group of herbicides comprising the active compounds listed below: 2-chloro-N-(ethoxymethyl)-N-(2-ethyl-6-methyl-phenyl)-acetamide (acetochlor), 5-(2-chloro-4-trifluoromethyl-phenoxy)-2-nitro-benzoic acid sodium salt (acifluorfen-sodium), 2-chloro-6-nitro-3-phenoxy-benzenamine (aclonifen), 2-chloro-N-(methoxymethyl)-N-(2,6-diethyl-phenyl)-acetamide (alachlor), N-ethyl-N′-i-propyl-6-methylthio-1,3,5-triazine-2,4-diamine (ametryn), 4-amino-N-(1,1-dimethyl-ethyl)-4,5-dihydro-3-(1-methyl-ethyl)-5-oxo-1H-1,2,4-triazole-1-carboxamide (amicarbazone), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(N-methyl-N-methylsulphonyl-sulphamoyl)-urea (amidosulfuron), 1H-1,2,4-triazol-3-amine (amitrole), 6-chloro-4-ethylamino-2-isopropylamino-1,3,5-triazine (atrazine), 2-[2,4-dichloro-5-(2-propinyloxy)-phenyl]-5,6,7,8-tetrahydro-1,2,4-triazolo-[4,3-a]-pyridin-3(2H)-one (azafenidin), N-(4,6-dimethoxy-pyrimidin-2-yl)-N-[1-methyl-4-(2-methyl-2H-tetrazol-5-yl)-1H-pyrazol-5-ylsulphonyl]-urea (azimsulfuron), N-benzyl-2-(4-fluoro-3-trifluoromethyl-phenoxy)-butanamide (beflubutamid), 4-chloro-2-oxo-3(2H)-benzothiazoleacetic acid (benazolin), N-butyl-N-ethyl-2,6-dinitro-4-trifluoromethyl-benzenamine (benfluralin), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(2-methoxycarbonyl-phenylmethylsulphonyl)-urea (bensulfuron), methyl 2-[2-[4-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H)-pyrimidinyl-)phenoxy]methyl]-5-ethyl-phenoxy-propanoate (benzfendizone), 3-(2-chloro-4-methylsulphonyl-benzoyl)-4-phenylthio-bicyclo-[3.2.1]-oct-3-en-2-one (benzobicyclon), ethyl N-benzoyl-N-(3,4-dichloro-phenyl)-DL-alaninate (benzoylprop-ethyl), 3-i-propyl-1H-2,1,3-benzothiadiazin-4(3H)-one (bentazone), methyl 5-(2,4-dichloro-phenoxy)-2-nitro-benzoate (bifenox), 2,6-bis-(4,6-dimethoxy-pyrimidin-2-yl-oxy)-benzoic acid sodium salt (bispyribac-sodium), 5-bromo-6-methyl-3-(1-methyl-propyl)-2,4(1H,3H)pyrimidinedione (bromacil), 2-bromo-3,3-dimethyl-N-(1-methyl-1-phenyl-ethyl)-butanamide (bromobutide), O-(2,4-dinitro-phenyl) 3,5-dibromo-4-hydroxy-benzaldehyde-oxime (bromofenoxim), 3,5-dibromo-4-hydroxy-benzonitrile (bromoxynil), N-butoxymethyl-2-chloro-N-(2,6-diethyl-phenyl)-acetamide (butachlor), [1,1-dimethyl-2-oxo-2-(2-propenyloxy)]-ethyl 2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H)-pyrimidinyl)-benzoate (butafenacil-allyl), 2-(1-ethoximino-propyl)-3-hydroxy-5-[2,4,6-trimethyl-3-(1-oxo-butyl)-phenyl]-2-cyclohexen-1-one (butroxydim), S-ethyl bis-(2-methyl-propyl)-thiocarbamate (butylate), N,N-diethyl-3-(2,4,6-trimethyl-phenylsulphonyl)-1H-1,2,4-triazole-1-carboxamide (cafenstrole), 2-[1-[(3-chloro-2-propenyl)-oxy-imino]-propyl]-3-hydroxy-5-(tetrahydro-2H-pyran-4-yl)-2-cyclohexen-1-one (caloxydim, tepraloxydim), 2-(4-chloro-2-fluoro-5-(2-chloro-2-ethoxycarbonyl-ethyl)-phenyl)-4-difluoromethyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one (carfentrazone-ethyl), 2,4-dichloro-1-(3-methoxy-4-nitro-phenoxy)-benzene (chlomethoxyfen), 3-amino-2,5-dichloro-benzoic acid (chloramben), N-(4-chloro-6-methoxy-pyrimdin-2-yl)-N′-(2-ethoxycarbonyl-phenylsulphonyl)-urea (chlorimuron-ethyl), 1,3,5-trichloro-2-(4-nitro-phenoxy)-benzene (chlomitrofen), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N′-(2-chloro-phenylsulphonyl)-urea (chlorsulfuron), N′-(3-chloro-4-methylphenyl)-N,N-dimethyl-urea (chlortoluron), ethyl 2-chloro-3-[2-chloro-5-(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)-phenyl]-2-propanoate (cinidon-ethyl), N-(4,6-dimethoxy-1,3,5-triazin-2-yl)-N′-(2-(2-methoxy-ethoxy)-phenylsulphonyl)-urea (cinosulfuron), 2-[1-[2-(4-chloro-phenoxy)-propoxyamino]butyl]-5-(tetrahydro-2H-thiopyran-3-yl)-1,3-cyclohexanedione (clefoxydim), (E,E)-(+)-2-[1-[[(3-chloro-2-propenyl)-oxy]-imino]-propyl]-3-hydroxy-2-cyclohexen-1-one (clethodim), prop-2-inyl (R)-2-[4-(5-chloro-3-fluoro-pyridin-2-yl-oxy)-phenoxy]-propanoate (clodinafop-propargyl), 3,6-dichloro-pyridine-2-carboxylic acid (clopyralid), methyl 3-chloro-2-[(5-ethoxy-7-fluoro[1,2,4]triazolo[1,5-c]pyrimidin-2-yl-sulphonyl)-amino]-benzoate (cloransulam-methyl), 2-chloro-4-ethylamino-6-(1-cyano-1-methyl-ethylamino)-1,3,5-triazine (cyanazine), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(2-cyclopropylcarbonyl-phenylsulphonyl)-urea (cyclosulfamuron), 2-(1-ethoximinobutyl)-3-hydroxy-5-(tetrahydro-2H-thiopyran-3-yl)-2-cyclohexen-1-one (cycloxydim), butyl (R)-2-[4-(4-cyano-2-fluoro-phenoxy)-phenoxy]-propanoate (cyhalofop-butyl), 2,4-dichloro-phenoxyacetic acid (2,4-D), 3,6-dichloro-2-methoxy-benzoic acid (dicamba), (R)-2-(2,4-dichloro-phenoxy)-propanoic acid (dichlorprop-P), methyl-2-[4-(2,4-dichloro-phenoxy)-phenoxy]-propanoate (diclofop-methyl), N-(2,6-dichloro-phenyl)-5-ethoxy-7-fluoro-[1,2,4]-triazolo-[1,5-c]-pyrimidine-2-sulphonamide (diclosulam), 1,2-dimethyl-3,5-diphenyl-1H-pyrazolium methylsulphate (difenzoquat), N-(2,4-difluoro-phenyl)-2-(3-trifluoromethyl-phenoxy)-pyridine-3-carboxamide (diflufenican), 2-[1-[(3,5-difluoro-phenyl)-amino-carbonyl-hydrazono]-ethyl]-pyridine-3-carboxylic acid (diflufenzopyr), S-(1-methyl-1-phenyl-ethyl) 1-piperidine-carbothioate (dimepiperate), 2-chloro-N-(2,6-dimethyl-phenyl)-N-(2-methoxy-ethyl)-acetamide (dimethachlor), (S—) 2-chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methyl-ethyl)-acetamide (S—) (dimethenamid), 2-amino-4-(1-fluoro-1-methyl-ethyl)-6-(1-methyl-2-(3,5-dimethyl-phenoxy)-ethylamino)-1,3,5-triazine (dimexyflam), N3,N3-diethyl-2,4-dinitro-6-trifluoromethyl-1,3-diamino-benzene (dinitramine), 6,7-dihydro-dipyrido[1,2-a:2′,1′-c]pyrazinediium (diquat), S,S-dimethyl 2-difluoromethyl-4-i-butyl-6-trifluoromethyl-pyridine-3,5-dicarbothioate (dithiopyr), N′-(3,4-dichloro-phenyl)-N,N-dimethyl-urea (diuron), 2-[2-(3-chloro-phenyl)-oxiranylmethyl]-2-ethyl-1H-indene-1,3(2H)-dione (epropodan), S-ethyl di-propylthiocarbamate (EPTC), S-(phenylmethyl) N-ethyl-N-(1,2-dimethylpropyl)-thiocarbamate (esprocarb), N-ethyl-N-(2-methyl-2-propenyl)-2,6-dinitro-4-trifluoromethyl-benzenamine (ethalfluralin), 2-ethoxy-1-methyl-2-oxoethyl (S)-2-chloro-5-(2-chloro-4-trifluoromethyl-phenoxy)-benzoate (ethoxyfen), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(2-ethoxy-phenoxysulphonyl)-urea (ethoxysulfuron), ethyl (R)-2-[4-(6-chloro-benzoxazol-2-yl-oxy)-phenoxy]-propanoate (fenoxaprop-(P)-ethyl), 4-(2-chloro-phenyl)-N-cyclohexyl-N-ethyl-4,5-dihydro-5-oxo-1H-tetrazole-1-carboxamide (fentrazamid), isopropyl N-benzoyl-N-(3-chloro-4-fluoro-phenyl)-DL-alaninate (flamprop-isopropyl), isopropyl N-benzoyl-N-(3-chloro-4-fluoro-phenyl)-L-alaninate (flamprop-isopropyl-L), methyl N-benzoyl-N-(3-chloro-4-fluoro-phenoxy)-DL-alaninate flamprop-methyl), N-(2,6-difluoro-phenyl)-8-fluoro-5-methoxy-[1,2,4]-triazolo-[1,5-c]-pyrimidine-2-sulphonamide (florasulam), butyl (R)-2-[4-(5-trifluoromethyl-pyridin-2-yl-oxy)-phenoxy]-propanoate (fluazifop, -butyl, —P-butyl), i-propyl 5-(4-bromo-1-methyl-5-trifluoromethyl-1H-pyrazol-3-yl)-2-chloro-4-fluoro-benzoate (fluazolate), 4,5-dihydro-3-methoxy-4-methyl-5-oxo-N-[(2-trifluoromethoxy-phenyl)-sulphonyl]-1H-1,2,4-triazole-1-carboxamide sodium salt (flucarbazone-sodium), N-(4-fluoro-phenyl)-N-i-propyl-2-(5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy)-acetamide (flufenacet), N-(2,6-difluoro-phenyl)-5-methyl-1,2,4-triazolo[1,5-a]-pyrimidine-2-sulphonamide (flumetsulam), pentyl[2-chloro-4-fluoro-5-(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)-phenoxy]-acetate (flumiclorac-pentyl), 2-[7-fluoro-3,4-dihydro-3-oxo-4-(2-propinyl)-2H-1,4-benzoxazin-6-yl]-4,5,6,7-tetrahydro-1H-isoindole-1,3-dione (flumioxazin), 2-[4-chloro-2-fluoro-5-[(1-methyl-2-propinyl)-oxy]-phenyl]-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)-dione (flumipropyn), 3-chloro-4-chloromethyl-1-(3-trifluoromethyl-phenyl)-2-pyrrolidinone (fluorochloridone), ethoxycarbonylmethyl 5-(2-chloro-4-trifluoromethyl-phenoxy)-2-nitro-benzoate (fluoroglycofen-ethyl), 1-(4-chloro-3-(2,2,3,3,3-pentafluoro-propoxymethyl)-phenyl)-5-phenyl-1H-1,2,4-triazole-3-carboxamide (flupoxam), 1-isopropyl-2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1(2H)-pyrimidyl)-benzoate (flupropacil), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(3-methoxycarbonyl-6-trifluoromethyl-pyridin-2-yl-sulphonyl)-urea sodium salt (flupyrsulfuron-methyl-sodium), 9-hydroxy-9H-fluorene-9-carboxylic acid (flurenol), (4-amino-3,5-dichloro-6-fluoro-pyridin-2-yl-oxy)-acetic acid (2-butoxy-1-methyl-ethyl ester, 1-methyl-heptyl ester) (fluroxypyr, -butoxypropyl, -meptyl), 5-methylamino-2-phenyl-4-(3-trifluoromethyl-phenyl)-3(2H)-furanone (flurtamone), methyl [(2-chloro-4-fluoro-5-(tetrahydro-3-oxo-1H,3H-[1,3,4]-thiadiazolo-[3,4-a]-pyridazin-1-yliden)-amino)-phenyl]-thioacetate (fluthiacet-methyl), 5-(2-chloro-4-trifluoromethyl-phenoxy)-N-methylsulphonyl-2-nitro-benzamide (fomesafen), 2-[[[[(4,6-dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-amino]-sulphonyl]-4-formylamino-N,N-dimethyl-benzamide (foramsulfuron), 2-amino-4-(hydroxymethylphosphinyl)-butanoic acid (ammonium salt) (glufosinate-(ammonium)), N-phosphonomethyl-glycine (isopropylammonium salt) (glyphosate, isopropylammonium), (R)-2-[4-(3-chloro-5-trifluoromethyl-pyridin-2-yl-oxy)-phenoxy]-propanoic acid (methyl ester, 2-ethoxy-ethyl ester, butyl ester) (haloxyfop, -methyl, —P-methyl, -ethoxyethyl, -butyl), 3-cyclohexyl-6-dimethylamino-1-methyl-1,3,5-triazine-2,4(1H,3H)-dione (hexazinone), methyl 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-4-methyl-benzoate (imazamethabenz-methyl), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5-methyl-pyridine-3-carboxylic acid (imazamethapyr), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5-methoxymethyl-pyridine-3-carboxylic acid (imazamox), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-quinoline-3-carboxylic acid (imazaquin), 2-(4,5-dihydro-4-methyl-4-i-propyl-5-oxo-1H-imidazol-2-yl)-5-ethyl-pyridine-3-carboxylic acid (imazethapyr), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(2-chloro-imidazo-[1,2-a]-pyridin-3-yl-sulphonyl)-urea (imazosulfuron), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N′-(5-iodo-2-methoxycarbonyl-phenylsulphonyl)-urea sodium salt (iodosulfuron-methyl-sodium), 4-hydroxy-3,5-diiodo-benzonitrile (ioxynil), N,N-dimethyl-N-(4-isopropyl-phenyl)-urea (isoproturon), N-(3-(1-ethyl-1-methyl-propyl)-isoxazol-5-yl)-2,6-dimethoxy-benzamide (isoxaben), (4-chloro-2-methylsulphonyl-phenyl)-(5-cyclopropyl-isoxazol-4-yl)-methanone (isoxachlortole), (5-cyclopropyl-isoxazol-4-yl)-(2-methylsulphonyl-4-trifluoromethyl-phenyl)-methanone (isoxaflutole), 2-[2-[4-[(3,5-dichloro-2-pyridinyl)-oxy]-phenoxy]-1-oxo-propyl]-isoxazolidine (isoxapyri-fop), (2-ethoxy-1-methyl-2-oxo-ethyl)-5-(2-chloro-4-trifluoromethyl-phenoxy)-2-nitro-benzoate (lactofen), N′-(3,4-dichloro-phenyl)-N-methoxy-N-methyl-urea (linuron), (4-chloro-2-methyl-phenoxy)-acetic acid (MCPA), 2-(4-chloro-2-methyl-phenoxy)-propionic acid (mecoprop), 2-(2-benzothiazolyloxy)-N-methyl-N-phenyl-acetamide (mefenacet), methyl 2-[[[[(4,6-dimethoxy-2-pyrimidinyl)amino)carbonyl]amino]sulphonyl]-4-[[(methylsulphonyl)amino]methyl]-benzoate (mesosulfuron), 2-(4-methylsulphonyl-2-nitro-benzoyl)-1,3-cyclohexanedione (mesotrione), 4-amino-3-methyl-6-phenyl-1,2,4-triazin-5(4H)-one (metamitron), 2-chloro-N-(2,6-dimethyl-phenyl)-N-(1H-pyrazol-1-yl-methyl)-acetamide (metazachlor), N′-(4-(3,4-dihydro-2-methoxy-2,4,4-trimethyl-2H-1-benzopyran-7-yl-oxy)-phenyl)-N-methoxy-N-methyl-urea (metobenzuron), N′-(4-bromophenyl)-N-methoxy-N-methyl urea (metobromuron), (S)-2-chloro-N-(2-ethyl-6-methyl-phenyl)-N-(2-methoxy-1-methyl-ethyl)-acetamide (metolachlor, S-metolachlor), N-(2,6-dichloro-3-methyl-phenyl)-5,7-dimethoxy-1,2,4-triazolo[1,5-a]-pyrimidine-2-sulphonamide (metosulam), N′-(3-chloro-4-methoxy-phenyl)-N,N-di-ethyl-urea (metoxuron), 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-one (metribuzin), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N′-(2-methoxycarbonyl-phenylsulphonyl)-urea (metsulfuron-methyl), S-ethyl-hexahydro-1H-azepine-1-carbothioate (molinate), 2-(2-naphthyloxy)-N-phenyl-propanamide (naproanilide), N-butyl-N′-(3,4-dichloro-phenyl)-N-methyl-urea (neburon), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(3-dimethylcarbamoyl-pyridin-2-yl-sulphonyl)-urea (nicosulfuron), 4-chloro-5-methylamino-2-(3-trifluoromethyl-phenyl)-3(2H)-pyridazinone (norflurazon), S-(2-chloro-benzyl)-N,N-diethyl-thiocarbamate (orbencarb), 4-dipropylamino-3,5-dinitro-benzenesulphonamide (oryzalin), 3-[2,4-dichloro-5-(2-propinyloxy)-phenyl]-5-(t-butyl)-1,3,4-oxadiazol-2(3H)-one (oxadiargyl), 3-[2,4-dichloro-5-(1-methyl-ethoxy)-phenyl]-5-(t-butyl)-1,3,4-oxadiazol-2(3H)-one (oxadiazon), N-(4,6-dimethyl-pyrimidin-2-yl)-N′-(2-oxetan-3-yl-oxycarbonyl-phenylsulphonyl)-urea (oxasulfuron), 3-[1-(3,5-dichloro-phenyl)-1-i-propyl]-2,3-dihydro-6-methyl-5-phenyl-4H-1,3-oxazin-4-one (oxaziclomefone), 2-chloro-1-(3-ethoxy-4-nitro-phenoxy)-4-trifluoromethylbenzene (oxyfluorfen), 1,1′-dimethyl-4,4′-bipyridinium (paraquat), 1-amino-N-(1-ethyl-propyl)-3,4-dimethyl-2,6-dinitro-benzene (pendimethalin), 4-(t-butyl)-N-(1-ethyl-propyl)-2,6-dinitro-benzenamine (pendralin), 4-amino-3,5,6-trichloro-pyridine-2-carboxylic acid (picloram), N-(4-fluoro-phenyl)-6-(3-trifluoromethyl-phenoxy)-pyridine-2-carboxamide (picolinafen), 2-chloro-N-(2,6-diethyl-phenyl)-N-(2-propoxy-ethyl)-acetamide (pretilachlor), N-(4,6-bis-difluoromethoxy-pyrimidin-2-yl)-N′-(2-methoxycarbonyl-phenylsulphonyl)-urea (primisulfuron-methyl), 1-chloro-N-[2-chloro-4-fluoro-5-[(6S,7aR)-6-fluorotetrahydro-1,3-dioxo-1H-pyrrolo[1,2-c]imidazol-2(3H)-yl]-phenyl]-methanesulphonamide (profluazol), 2-chloro-N-isopropyl-N-phenyl-acetamide (propachlor), N-(3,4-dichlorophenyl)-propanamide (propanil), (R)-[2-[[(1-methylethylidene)-amino]-oxy]-ethyl]-2-[4-(6-chloro-2-quinoxalinyloxy)-phenoxy]-propanoate (propaquiza-fop), 2-chloro-N-(2-ethyl-6-methyl-phenyl)-N-[(1-methyl-ethoxy)-methyl]-acetamide (propisochlor), methyl 2-[[[(4,5-dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl]-carbonyl]-amino]-sulphonyl]-benzoate sodium salt (propoxycarbazone-sodium), S-phenylmethyl N,N-dipropyl-thiocarbamate (prosulfocarb), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N′-(2-(3,3,3-trifluoro-propyl)-phenylsulphonyl)-urea (prosulfuron), ethyl [2-chloro-5-(4-chloro-5-difluoromethoxy-1-methyl-1H-pyrazol-3-yl)-4-fluoro-phenoxy]-acetate (pyraflufen-ethyl), 1-(3-chloro-4,5,6,7-tetrahydro-pyrazolo[1,5-a]pyridin-2-yl)-5-(methyl-2-propinylamino)-1H-pyrazole-4-carbonitrile (pyrazogyl), 4-(2,4-dichloro-benzoyl)-1,3-dimethyl-5-(4-methyl-phenylsulphonyloxy)-pyrazole (pyrazolate), 4-(2,4-dichloro-benzoyl)-1,3-dimethyl-5-(phenylcarbonylmethoxy)-pyrazole (pyrazoxyfen), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(4-ethoxycarbonyl-1 methyl-pyrazol-5-yl-sulphonyl)-urea (pyrazosulfuron-ethyl), O-[2,6-bis-(4,6-dimethoxy-pyrimidin-2-yl-oxy)-benzoyl]diphenylmethanone-oxime (pyribenzoxim), 6-chloro-3-phenyl-4-pyridazinol (pyridafol), O-(6-chloro-3-phenyl-pyridazin-4-yl) S-octyl thiocarbonate (pyridate), 6-chloro-3-phenyl-pyridazin-4-ol (pyridatol), 7-[(4,6-dimethoxy-2-pyrimidinyl)-thio]-3-methyl-1 (3H)-iso-benzofuranone (Pyriftalid), methyl 2-(4,6-dimethoxy-pyrimidin-2-yl-oxy)-benzoate (pyriminobac-methyl), 2-chloro-6-(4,6-dimethoxy-pyrimidin-2-ylthio)-benzoic acid sodium salt (pyrithiobac-sodium), 3,7-dichloro-quinoline-8-carboxylic acid (quinchlorac), 7-chloro-3-methyl-quinoline-8-carboxylic acid (quinmerac), 2-[4-(6-chloro-2-quinoxalinyloxy)-phenoxy]-propanoic acid (ethyl-ester, tetrahydro-2-furanyl-methyl ester) (quizalofop, -ethyl, —P-ethyl, —P-tefuryl), N-(4,6-dimethoxy-pyrimidin-2-yl)-N-(3-ethylsulphonyl-pyridin-2-yl-sulphonyl)-urea (rimsulfuron), 2-(1-ethoximinobutyl)-5-(2-ethylthiopropyl)-3-hydroxy-2-cyclohexen-1-one (sethoxydim), 6-chloro-2,4-bis-ethylamino-1,3,5-triazine (simazin), 2-(2-chloro-4-methylsulphonyl-benzoyl)-cyclohexane-1,3-dione (sulcotrione), 2-(2,4-dichloro-5-methylsulphonylamino-phenyl)-4-difluoromethyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one (sulfentrazone), methyl 2-[[[[(4,6-dimethyl-2-pyrimidinyl)amino]carbonyl]amino]sulphonyl]-benzoate (sulfometuron-methyl), N-phosphonomethyl-glycine-trimethylsulphonium (sulfosate), N-(4,6-dimethoxy-pyrimidin-2-yl)-N′-(2-ethylsulphonyl)-imidazo[1,2-a]pyridine-3-sulphonamide (sulfosulfuron), 6-chloro-4-ethylamino-2-tert-butylamino-1,3,5-triazine (terbuthylazine), 2-tert-butylamino-4-ethylamino-6-methylthio-1,3,5-triazine (terbutryn), 2-chloro-N-(2,6-dimethyl-phenyl)-N-(3-methoxy-2-thienyl-methyl)-acetamide (thenylchlor), methyl 2-difluoromethyl-5-(4,5-dihydro-thiazol-2-yl)-4-(2-methyl-propyl)-6-trifluoromethyl-pyridine-3-carboxylate (thiazopyr), 6-(6,7-dihydro-6,6-dimethyl-3H,5H-pyrrolo[2,1-c]-1,2,4-thiadiazol-3-ylideneamino)-7-fluoro-4-(2-propinyl)-2H-1,4-benzoxazin-3(4H)-one (thidiazimin), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N′-(2-methoxy-carbonyl-thien-3-yl-sulphonyl)-urea (thifensulfuron-methyl), 2-(ethoximino-propyl)-3-hydroxy-5-(2,4,6-trimethyl-phenyl)-2-cyclohexen-1-one (tralkoxydim), S-(2,3,3-trichloro-2-propenyl) diisopropylcarbamothioate (triallate), N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N′-[2-(2-chloro-ethoxy)-phenylsulphonyl]-urea (triasulfuron), N-methyl-N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N′-(2-methoxycarbonyl-phenylsulphonyl)-urea (tribenuron-methyl), (3,5,6-trichloro)-pyridin-2-yl-oxy-acetic acid (triclopyr), 2-(3,5-dichloro-phenyl)-2-(2,2,2-trichloro-ethyl)-oxirane (tridiphane), N-[[(4,6-dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-3-(2,2,2-trifluoro-ethoxy)-2-pyridinesulphonamide sodium salt (trifloxysulfuron), 1-amino-2,6-dinitro-N,N-dipropyl-4-trifluoromethyl-benzene (trifluralin), N-[4-dimethylamino-6-(2,2,2-trifluoro-ethoxy)-1,3,5-triazin-2-yl]-N′-(2-methoxycarbonyl-phenylsulphonyl)-urea (triflusulfuron-methyl), N-(4-methoxy-6-trifluoromethoxy-1,3,5-triazin-2-yl)-N′-(2-trifluoromethyl-phenylsulphonyl)-urea (tritosulfuron), N-[[(4,6-dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-3-(N-methyl-N-methylsulphonyl-amino)-2-pyridinesulphonamide, 4-[4,5-dihydro-4-methyl-5-oxo-(3-trifluoromethyl)-1H-1,2,4-triazol-1-yl]-2-[(ethylsulphonyl)amino]-5-fluoro-benzenecarbothioamide (“active compounds of Group 2”), and/or (c) a compound which improves crop plant compatibility from the group of compounds below: 4-dichloroacetyl-1-oxa-4-aza-spiro[4.5]-decane (AD-67), 1-dichloroacetyl-hexahydro-3,3,8a-trimethylpyrrolo[1,2-a]-pyrimidin-6(2H)-one (BAS-145138), 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine (benoxacor), 1-methyl-hexyl 5-chloro-quinoxalin-8-oxy-acetate (cloquintocet-mexyl), α-(cyanomethoximino)-phenylacetonitrile (cyometrinil), 2,4-dichlorophenoxy-acetic acid (2,4-D), 2,2-dichloro-N-(2-oxo-2-(2-propenylamino)-ethyl)-N-(2-propenyl)-acetamide (DKA-24), 2,2-dichloro-N,N-di-2-propenyl-acetamide (dichlormid), N-(4-methyl-phenyl)-N′-(1-methyl-1-phenyl-ethyl)-urea (dymron), 4,6-dichloro-2-phenyl-pyrimidine (fenclorim), ethyl 1-(2,4-dichloro-phenyl)-5-trichloromethyl-1H-1,2,4-triazole-3-carboxylate (fenchlorazol-ethyl), phenylmethyl 2-chloro-4-trifluoromethyl-thiazole-5-carboxylate (flurazole), 4-chloro-N-(1,3-dioxolan-2-yl-methoxy)-α-trifluoro-acetophenone oxime (fluxofenim), 3-dichloroacetyl-5-(2-furanyl)-2,2-dimethyl-oxazolidine (furilazole, MON-13900), ethyl 4,5-dihydro-5,5-diphenyl-3-isoxazolecarboxylate (isoxadifen-ethyl), (4-chloro-2-methyl-phenoxy)-acetic acid (MCPA), (+−)-2-(4-chloro-2-methylphenoxy)propanoic acid (mecoprop), diethyl 1-(2,4-dichlorophenyl)-4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylate (mefenpyr-diethyl), 2-dichloromethyl-2-methyl-1,3-dioxolane (MG-191), 1,8-naphthalic anhydride, α-(1,3-dioxolan-2-yl-methoximino)-phenylacetonitrile (oxabetrinil), 2,2-dichloro-N-(1,3-dioxolan-2-yl-methyl)-N-(2-propenyl)-acetamide (PPG-1292), 3-dichloroacetyl-2,2,5-trimethyl-oxazolidine (R-29148), N-cyclopropyl-4-[[(2-methoxy-5-methyl-benzoyl)-amino]-sulphonyl]-benzamide, N-[(4-methoxyacetylamino)-phenyl]-sulphonyl-2-methoxy-benzamide and N-[(4-methylaminocarbonylamino)-phenyl]-sulphonyl-2-methoxy-benzamide (“active compounds of Group 3”).
 2. Herbicidal compositions according to claim 1, characterized in that they comprise, as active compounds of Group 1, compounds of the formula (I) in which R¹ represents hydrogen, amino or in each case optionally cyano-, fluorine-, chlorine- methoxy- or ethoxy-substituted methyl, ethyl, n- or i-propyl, R² represents in each case optionally fluorine- and/or chlorine-substituted methyl, ethyl, n- or i-propyl, R³ represents hydrogen, fluorine, chlorine, bromine or in each case optionally fluorine- and/or chlorine-substituted methyl, ethyl, n- or i-propyl, R⁴ represents hydrogen, cyano, fluorine, chlorine or bromine, R⁵ represents cyano, thiocarbamoyl, fluorine, chlorine or bromine, and R⁶ represents nitro, cyano, carboxyl, carbamoyl, thiocarbamoyl, hydroxyl, mercapto, amino, hydroxyamino, aminosulphonyl, fluorine, chlorine, bromine, represents in each case optionally cyano-, carboxyl-, hydroxyl-, methoxy-, ethoxy-, n- or i-propoxy-, acetyl-, propionyl-, n- or i-butyroyl-, methoxycarbonyl-, ethoxycarbonyl-, n- or i-propoxycarbonyl-, allyloxycarbonyl- or propargyloxycarbonyl-substituted methyl, ethyl, n- or i-propyl, n-, i- or s-butyl, methoxy, ethoxy, n- or i-propoxy, n-, i- or s-butoxy, methylthio, ethylthio, n- or i-propylthio, n-, i- or s-butylthio, methylsulphinyl, ethylsulphinyl, methylsulphonyl, ethylsulphonyl, acetyl, propionyl, n- or i-butyroyl, methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl, methylamino, ethylamino, n- or i-propylamino, n-, i- or s-butylamino, represents in each case optionally cyano-, carboxyl-, fluorine-, chlorine-, bromine-, methoxycarbonyl- and/or ethoxycarbonyl-substituted ethenyl, propenyl, butenyl, ethinyl, propinyl, butinyl, propenyloxy, butenyloxy, propinyloxy or butinyloxy, represents in each case, optionally fluorine- and/or chlorine-, methoxy-, ethoxy-, n- or i-propoxy-substituted acetylamino, propionylamino, n- or i-butyroylamino, methoxycarbonylamino, ethoxycarbonylamino, n- or i-propoxycarbonylamino, methylsulphonylamino, ethylsulphonylamino, n- or i-propylsulphonylamino, n-, i-, s- or t-butylsulphonylamino, N,N-bis-methylsulphonyl-amino, N,N-bis-ethylsulphonyl-amino, N-ethylsulphonyl-N-methylsulphonyl-amino, N-methylsulphonyl-N-n-propylsulphonyl-amino, N-methylsulphonyl-N-i-propylsulphonyl-amino, N-acetyl-N-methylsulphonyl-amino, N-propionyl-N-methylsulphonyl-amino, N-n-butyroyl-N-methylsulphonyl-amino, N-i-butyroyl-N-methylsulphonyl-amino, N-s-butyroyl-N-methylsulphonyl-amino, N-t-butyroyl-N-methylsulphonyl-amino, N-(2,2-dimethyl-propanoyl)-N-ethylsulphonyl-amino, N-(2-methylpropanoyl)-N-ethylsulphonyl-amino, N-acetyl-N-ethylsulphonyl-amino, N-propionyl-N-ethylsulphonyl-amino, N-n-butyroyl-N-ethylsulphonyl-amino, N-i-butyroyl-N-ethylsulphonyl-amino, N-s-butyroyl-N-ethylsulphonyl-amino, N-t-butyroyl-N-ethylsulphonyl-amino, or represents in each case optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, n- or i-propyl-, n-, i-, s- or t-butyl-, trifluoromethyl-, methoxy-, ethoxy-, n- or i-propoxy-, difluoromethoxy- or trifluoromethoxy-substituted N-phenylcarbonyl-N-methylsulphonyl-amino, N-phenylcarbonyl-N-ethylsulphonyl-amino, N-thienylcarbonyl-N-methylsulphonyl-amino or N-thienylcarbonyl-N-ethyl-sulphonyl-amino.
 3. Herbicidal compositions according to claim 1, characterized in that they comprise, as active compounds of Group 1, compounds of the formula (I) in which, R¹ represents hydrogen, amino, methyl or ethyl, R² represents in each case fluorine- and/or chlorine-substituted methyl or ethyl, R³ represents hydrogen, fluorine, chlorine, bromine or in each case optionally fluorine- and/or chlorine-substituted methyl or ethyl, R⁴ represents hydrogen, fluorine or chlorine, R⁵ represents cyano, thiocarbamoyl, chlorine or bromine, and R⁶ represents nitro, cyano, carboxyl, carbamoyl, thiocarbamoyl, hydroxyl, mercapto, amino, hydroxyamino, aminosulphonyl, fluorine, chlorine, bromine, represents in each case optionally cyano-, carboxyl-, hydroxyl-, methoxy-, ethoxy-, acetyl-, propionyl-, methoxycarbonyl- and/or ethoxycarbonyl, n- or i-propoxycarbonyl-, allyloxycarbonyl- or propargyloxycarbonyl-substituted methyl, ethyl, n- or i-propyl, methoxy, ethoxy, n- or i-propoxy, methylthio, ethylthio, n- or i-propylthio, methylsulphinyl, ethylsulphinyl, methylsulphonyl, ethylsulphonyl, acetyl, propionyl, n- or i-butyroyl, methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl, methylamino, ethylamino, n- or i-propylamino, represents in each case optionally cyano-, carboxyl-, fluorine-, chlorine-, bromine-, methoxycarbonyl- and/or ethoxycarbonyl-substituted ethenyl, propenyl, ethinyl, propinyl, propenyloxy or propinyloxy, represents in each case optionally fluorine- and/or chlorine-, methoxy- or ethoxy-substituted acetylamino, propionylamino, methoxycarbonylamino, ethoxycarbonylamino, methylsulphonylamino, ethylsulphonylamino, n- or i-propylsulphonylamino, n-, i-, s- or t-butylsulphonylamino, N,N-bis-methylsulphonyl-amino, N,N-bis-ethylsulphonyl-amino, N-ethylsulphonyl-N-methylsulphonyl-amino, N-methylsulphonyl-N-n-propylsulphonyl-amino, N-methylsulphonyl-N-i-propylsulphonyl-amino, N-acetyl-N-methylsulphonyl-amino, N-propionyl-N-methylsulphonyl-amino, N-(2,2-dimethyl-propanoyl)-N-ethylsulphonyl-amino, N-(2-methylpropanoyl)-N-ethylsulphonyl-amino, N-n-butyroyl-N-methylsulphonyl-amino, N-i-butyroyl-N-methylsulphonyl-amino, N-s-butyroyl-N-methylsulphonyl-amino, N-t-butyroyl-N-methylsulphonyl-amino, N-acetyl-N-ethylsulphonyl-amino, N-propionyl-N-ethylsulphonyl-amino, N-n-butyroyl-N-ethylsulphonyl-amino, N-i-butyroyl-N-ethylsulphonyl-amino, N-s-butyroyl-N-ethylsulphonyl-amino, N-t-butyroyl-N-ethylsulphonyl-amino, or represents in each case optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, trifluoromethyl-, methoxy-, ethoxy-, difluoromethoxy- or trifluoromethoxy-substituted N-phenylcarbonyl-N-methylsulphonyl-amino, N-phenylcarbonyl-N-ethylsulphonyl-amino, N-thienylcarbonyl-N-methyl-sulphonyl-amino or N-thienylcarbonyl-N-ethylsulphonyl-amino.
 4. Herbicidal compositions according to claim 1, characterized in that they comprise, as active compounds of Group 1, compounds of the formula (I) in which R¹ represents amino, R² represents trifluoromethyl, R³ represents hydrogen, chlorine or methyl, R⁴ represents fluorine, R⁵ represents cyano or thiocarbamoyl, and R⁶ represents in each case optionally fluorine- and/or chlorine-substituted methylsulphonylamino, ethylsulphonylamino, n- or i-propylsulphonylamino, n-, i-, s- or t-butylsulphonylamino, N,N-bis-methylsulphonyl-amino, N,N-bis-ethylsulphonyl-amino, N-ethylsulphonyl-N-methylsulphonyl-amino, N-methylsulphonyl-N-n-propylsulphonyl-amino, N-methylsulphonyl-N-i-propylsulphonyl-amino, N-acetyl-N-methylsulphonyl-amino, N-propionyl-N-methylsulphonyl-amino, N-(2,2-dimethyl-propanoyl)-N-ethylsulphonyl-amino, N-(2-methylpropanoyl)-N-ethylsulphonyl-amino, N-n-butyroyl-N-methylsulphonyl-amino, N-i-butyroyl-N-methylsulphonyl-amino, N-s-butyroyl-N-methylsulphonyl-amino, N-t-butyroyl-N-methylsulphonyl-amino, N-methoxyacetyl-N-methylsulphonyl-amino, N-acetyl-N-ethylsulphonyl-amino, N-propionyl-N-ethylsulphonyl-amino, N-n-butyroyl-N-ethylsulphonyl-amino, N-i-butyroyl-N-ethylsulphonyl-amino, N-s-butyroyl-N-ethylsulphonyl-amino, N-t-butyroyl-N-ethylsulphonyl-amino, N-methoxyacetyl-N-ethylsulphonylamino, or represents in each case optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, Trifluoromethyl-, methoxy-, ethoxy-, difluoromethoxy- or trifluoromethoxy-substituted N-phenylcarbonyl-N-methylsulphonyl-amino, N-phenylcarbonyl-N-ethylsulphonyl-amino, N-thienylcarbonyl-N-methylsulphonyl-amino or N-thienylcarbonyl-N-ethylsulphonyl-amino.
 5. Herbicidal compositions according to claim 1, characterized in that they comprise, as active compounds of Group 1, compounds of the formula (I) in which R¹ represents methyl, R² represents trifluoromethyl, R³ represents hydrogen, chlorine or methyl, R⁴ represents fluorine, R⁵ represents thiocarbamoyl, and R⁶ represents in each case optionally fluorine- and/or chlorine-substituted methylsulphonylamino, ethylsulphonylamino, n- or i-propylsulphonylamino, n-, i-, s- or t-butylsulphonylamino, N,N-bis-methylsulphonyl-amino, N,N-bis-ethylsulphonyl-amino, N-ethylsulphonyl-N-methylsulphonyl-amino, N-methylsulphonyl-N-n-propylsulphonyl-amino, N-methylsulphonyl-N-i-propylsulphonyl-amino, N-acetyl-N-methylsulphonyl-amino, N-propionyl-N-methylsulphonyl-amino, N-(2,2-dimethyl-propanoyl)-N-ethylsulphonyl-amino, N-(2-methylpropanoyl)-N-ethylsulphonyl-amino, N-n-butyroyl-N-methylsulphonyl-amino, N-i-butyroyl-N-methylsulphonyl-amino, N-s-butyroyl-N-methylsulphonyl-amino, N-t-butyroyl-N-methylsulphonyl-amino, N-methoxyacetyl-N-methylsulphonyl-amino, N-acetyl-N-ethylsulphonyl-amino, N-propionyl-N-ethylsulphonyl-amino, N-n-butyroyl-N-ethylsulphonyl-amino, N-i-butyroyl-N-ethylsulphonyl-amino, N-s-butyroyl-N-ethylsulphonyl-amino, N-t-butyroyl-N-ethylsulphonyl-amino, N-methoxyacetyl-N-ethylsulphonyl-amino, or represents in each case optionally cyano-, fluorine-, chlorine-, bromine-, methyl-, ethyl-, trifluoromethyl-, methoxy-, ethoxy-, difluoromethoxy- or trifluoromethoxy-substituted N-phenylcarbonyl-N-methylsulphonyl-amino, N-phenylcarbonyl-N-ethylsulphonyl-amino, N-thienylcarbonyl-N-methylsulphonyl-amino or N-thienylcarbonyl-N-ethylsulphonyl-amino.
 6. Herbicidal compositions according to claim 1, characterized in that they comprise, as active compounds of Group 1, compounds of the formula (I) in which R¹ represents amino or methyl, R² represents trifluoromethyl, R³ represents hydrogen, chlorine or methyl, R⁴ represents hydrogen, fluorine or chlorine, R⁵ represents cyano, thiocarbamoyl or chlorine, and R⁶ represents carboxyl, carbamoyl, thiocarbamoyl, hydroxyl, mercapto, amino, fluorine, chlorine, bromine, represents in each case optionally cyano-, carboxyl-, hydroxyl-, methoxy-, ethoxy-, acetyl-, propionyl-, methoxycarbonyl-, ethoxycarbonyl-, n- or i-propoxycarbonyl-, allyloxycarbonyl- or propargyloxycarbonyl-substituted methyl, ethyl, n- or i-propyl, methoxy, ethoxy, n- or i-propoxy, methylthio, ethylthio, n- or i-propylthio, methylsulphinyl, ethylsulphinyl, methylsulphonyl, ethylsulphonyl, acetyl, propionyl, n- or i-butyroyl, methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl, methylamino, ethylamino, n- or i-propylamino, N-(2,2-dimethyl-propanoyl)-N-ethylsulphonyl-amino, N-(2-methylpropanoyl)-N-ethylsulphonyl-amino, or represents in each case optionally cyano-, carboxyl-, fluorine-, chlorine-, bromine-, methoxycarbonyl- and/or ethoxycarbonyl-substituted ethenyl, propenyl, ethinyl, propinyl, propenyloxy or propinyloxy.
 7. Herbicidal compositions according to claim 1, characterized in that they comprise, as active compounds of Group 1, at least one of the following compounds: 1,1-dimethyl-2-oxo-2-(2-propenyloxy)-ethyl 2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1(2H)-pyrimidinyl)-benzoate, 5-fluoro-4-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1(2H)-pyrimidinyl)-2-[(1-methyl-2-propinyl)-oxy]-benzonitrile, N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(2,2-dimethyl-propanoyl)-1-ethanesulphonamide, N-[2-cyano-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-phenyl]-N-(4-methoxy-benzoyl)-ethanesulfonamide, N-[5-(3-amino-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl)-2-cyano-4-fluoro-phenyl]-N-(2-thienyl-carbonyl)-1-ethanesulphonamide, 2-(ethylsulphonylamino)-5-fluoro-4-[3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-1 (2H)-pyrimidinyl]-benzenecarbothioamide.
 8. Herbicidal compositions according to any one of claims 1 to 7, characterized in that they comprise, as active compounds of Group 2, at least one compound from the group of compounds below: acetochlor, alachlor, amicarbazone, amitrole, atrazine, bromacil, carfentrazone-ethyl, chlorimuron-ethyl, clodinafop-propargyl, cyanazine, diclosulam, dimethenamid, S-dimethenamid, diuron, EPTC, fenoxaprop-P-ethyl, fentrazamide, flucarbazone-sodium, flufenacet, flumetsulam, glufosinate-ammonium, glyphosate-isopropylammonium, imazamox, imazaquin, imazethapyr, isoxaflutole, mesotrione, metolachlor, S-metolachlor, metribuzin, nicosulfuron, norflurazon, pendimethalin, propoxycarbazone-sodium, rimsulfuron, simazin, sulfometuron-methyl, sulcotrione, sulfentrazone, sulfosate, terbuthylazine, thifensulfuron-methyl, trifluralin, 4-[4,5-dihydro-4-methyl-5-oxo-(3-trifluoromethyl)-1H-1,2,4-triazol-1-yl]-2-[(ethylsulphonyl)amino]-5-fluoro-benzenecarbothioamide.
 9. Herbicidal compositions according to any one, of claims 1 to 8, characterized in that they comprise, as active compound of Group 3, at least one of the compounds from the group of compounds below: 1-methyl-hexyl 5-chloro-quinoxalin-8-oxy-acetate (cloquintocet-mexyl), ethyl 4,5-dihydro-5,5-diphenyl-3-isoxazole-carboxylate (isoxadifen-ethyl), diethyl 1-(2,4-dichloro-phenyl)-4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylate (mefenpyr-diethyl), 4-dichloroacetyl-1-oxa-4-aza-spiro[4.5]-decane (AD-67), 1-dichloroacetyl-hexahydro-3,3,8a-trimethylpyrrolo[1,2-a]-pyrimidin-6(2H)-one (BAS-145138), 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine (benoxacor), 2,2-dichloro-N,N-di-2-propenyl-acetamide (dichlormid), 3-dichloroacetyl-5-(2-furanyl)-2,2-dimethyl-oxazolidine (furilazole, MON-13900) and 3-dichloroacetyl-2,2,5-trimethyl-oxazolidine (R-29148).
 10. Use of a composition according to any of claims 1 to 9 for controlling undesirable plants.
 11. Method for controlling undesirable plants, characterized in that compositions according to any of claims 1 to 9 are allowed to act on the undesirable plants and/or their habitat.
 12. Process for preparing a herbicidal composition, characterized in that a composition according to any of claims 1 to 9 is mixed with surfactants and/or extenders. 